| 5,6-二溴甲基苯并咪唑的合成研究 |
| |
| 引用本文： | 张小英,曾和平,曾志,霍延平. 5,6-二溴甲基苯并咪唑的合成研究[J]. 化学世界, 2002, 43(9): 479-481 |
| |
| 作者姓名： | 张小英 曾和平 曾志 霍延平 |
| |
| 作者单位： | 1. 深圳卫校,广东,深圳,518000;华南师范大学化学系,广东,广州,510631
2. 华南师范大学化学系,广东,广州,510631 |
| |
| 基金项目： | 国家自然科学基金项目 (2 0 0 710 12 )，广东省自然科学基金项目 (0 0 0 70 0 ) |
| |
| 摘 要： | 5,6-二溴甲基苯并咪唑是 Diels- Alder环加成反应形成含杂原子的 C60 衍生物的重要中间体。以 5 ,6-二甲基苯并咪唑在 AIBN的催化下与 NBS发生自由基反应 ,得到 5 ,6-二溴甲基苯并咪唑 ,用 TLC分离产物 ,并用 FAB MS、FT- IR、UV对产物进行了结构表征
|
| 关 键 词： | 5,6-二溴甲基苯并咪唑 合成 结构表征 |
| 文章编号： | 0367-6358(2002)09-0479-03 |
| 修稿时间： | 2002-02-28 |
Study on the Synthesis of 5,6-Bis(bromomethyl) benzimidazole |
| |
| ZHANG Xiao ying ,,ZENG He ping ,ZENG Zhi ,HUO Yan ping. Study on the Synthesis of 5,6-Bis(bromomethyl) benzimidazole[J]. Chemical World, 2002, 43(9): 479-481 |
| |
| Authors: | ZHANG Xiao ying ZENG He ping ZENG Zhi HUO Yan ping |
| |
| Affiliation: | ZHANG Xiao ying 1,2,ZENG He ping 2,ZENG Zhi 2,HUO Yan ping 2 |
| |
| Abstract: | 5,6-Bis(bromomethyl) benzimidazole is an important intermediate for making heterocyclic of [60] fullerene derivatives in Diels Alder reaction. Radical bromination of 5,6 dimethylbenzimidazole was carried out using N bromosuccinimide in the presence of azobisisiobutyronitrile. The product was separated and purified by TLC and 5,6 bis(bromomethyl)benzimidazole was obtained. The chemical structure of 5,6 bis(bromomethyl)benzimidazole was characterized by FAB MS, FT IR, UV techniques. |
| |
| Keywords: | 5 6-bis(bromomethyl)benzimidazole synthesis characterization |
| 本文献已被 CNKI 万方数据 等数据库收录！ |
|
