Hydrogen adsorption over Zeolite-like MOF materials modified by ion exchange |
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Authors: | G. Calleja,J.A. Botas,M. Sá nchez-Sá nchez,M.G. Orcajo |
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Affiliation: | 1. Department of Chemical and Energy Technology, ESCET, Universidad Rey Juan Carlos, C/Tulipán s/n, 28933 Móstoles, Madrid, Spain;2. Instituto de Catálisis y Petroleoquímica, CSIC, C/Marie Curie 2, 28049 Madrid, Spain |
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Abstract: | Novel porous Zeolite-like metal-organic framework (ZMOF) materials with Rho and Sod topologies are promising adsorbents for hydrogen storage due to their high surface area and, more importantly, to their capacity of being ion-exchanged, potentially changing their affinity for hydrogen. In this work, we have successfully synthesized both Rho and SodZMOF materials, optimizing experimental conditions for scaling-up the procedure already published to produce grams of material. The resultant materials were alkaline-cation-exchanged, widely characterized and finally tested as hydrogen adsorbents. |
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Keywords: | Zeolite-like metal-organic framework ZMOF Rho Sod Ion exchange Hydrogen adsorption |
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