Effect of polyoxometalate amount deposited on Pt/C electrocatalysts for CO tolerant electrooxidation of H2 in polymer electrolyte fuel cells

Polyoxometalate-deposited Pt/C electrocatalysts are prepared by impregnation with various amounts of polyoxometalate (POM) anions (from 2 to 16.7 wt.% PMo₁₂O₄₀^3–) on the Pt/C catalyst. The prepared electrocatalysts show a high CO electrooxidation performance over a half-cell system for CO stripping voltammetry, and CO tolerant electrooxidation of H₂ is further demonstrated over a proton exchange membrane fuel cell by using CO-containing H₂ gas feeds (0, 10, 50, and 100 ppm CO in H₂). In the CO stripping voltammograms, the onset and peak potentials for the CO oxidation appear to decrease as the POM deposition is increased, indicating that the electrooxidation of CO undergoes more efficiently on the catalyst surface with the deposited POMs on the Pt/C catalysts. In the single fuel cell tests with the CO-containing H₂ gases, the higher current density is also generated with the larger amounts of deposited POMs on the Pt/C catalysts. Importantly, the charge transfer resistance R_p appears to decrease monotonically with the POM amounts, which was measured by electrochemical impedance spectroscopy. Physico-chemical characterizations with electrocatalytic analyses show that the deposited POMs hardly affect the active phase of Pt catalyst itself but can help the electrooxidation of H₂ by efficiently oxidizing CO to prevent the Pt catalyst from poisoning. Consequently, this POM-deposited Pt/C catalyst can serve as a promising CO tolerant anode catalyst for the polymer electrolyte fuel cells that are operated with hydrocarbons-reformed H₂ fuel gases.