| 含环戊二烯络铁基团二苯并二噁英的合成 |
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| 引用本文： | 马国章,白国宝,周少卿.含环戊二烯络铁基团二苯并二噁英的合成[J].山西化工,2001,21(2):1-2. |
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| 作者姓名： | 马国章 白国宝 周少卿 |
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| 作者单位： | 1. 山西省应用化学研究所,太原,030027
2. 朔州师范学校 |
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| 摘 要： | 采用含环戊二烯络铁(FeCp)基团邻二氯苯和含羟基、巯基的二元酚类化合物合成含FeCp基团的二苯并二噁英.实验中,以N,N-二甲基甲酰胺(DMF)为溶剂,室温下,在K2CO3弱碱性介质中,产品收率高,副反应少,反应时间短.通过1H NMR和13C NMR对该类产品结构的研究表明产品纯度高;酚类的选择不同,H、C化学位移有一定差异.
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| 关 键 词： | 含环戊二烯络铁基团二苯并二噁英 合成 |
| 修稿时间： | 2001年1月9日 |
Synthesis of Dibenzo[1,4]dioxin Compounds with Cyclopentadienyliron Complex |
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| Ma Guozhang,Bai Guobao,Zhou Shaoqing.Synthesis of Dibenzo[1,4]dioxin Compounds with Cyclopentadienyliron Complex[J].Shanxi Chemical Industry,2001,21(2):1-2. |
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| Authors: | Ma Guozhang Bai Guobao Zhou Shaoqing |
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| Abstract: | Dibenzo1,4]dioxin compounds with cyclopentadienyliron complex were synthesized by cyclopentadienyliron complex of o-dichlorobenzene with o-dihydroxybenzene,2,3-dihydroxypyridine, 4-methyl-l,2-dimercaptobenzene in the presence of K2CO3 in DMF at room temperature. 1H NMR and 13C NMR showed that the products were pure and there were different chemical shifts if different starting materials were used. |
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| Keywords: | dibenzo[l 4]dioxin compounds with cyclopentadienyliron complex synthesis |
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