Mechanism of swift chemical sputtering: Comparison of Be/C/W dimer bond breaking |
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Authors: | K Nordlund C BjörkasK Vörtler A MeinanderA Lasa M MehineAV Krasheninnikov |
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Affiliation: | a Department of Physics, P.O. Box 43, FI-00014 University of Helsinki, Finland b Department of Applied Physics, P.O. Box 1100, FI-00076 Aalto University, Finland |
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Abstract: | Current and future tokamak-like fusion reactors include the three elements Be, C, and W as the plasma-facing materials. During reactor operation, also mixtures of all these elements will form. Hence it is important to understand the atom-level mechanisms of physical and chemical sputtering in these materials. We have previously shown that athermal low-energy sputtering of pure C and Be can be understood by the swift chemical sputtering mechanism, where an incoming H (or D or T) ion enters between two atoms and pushes them apart. In the current article, we examine the model system of D impacting on a single dimer to determine the detailed mechanism of bond breaking and its probability for the Be2, C2, W2, WC, BeW, and BeC dimers. The results are found to correlate well with recent experiments and simulations of sputtering of the corresponding bulk materials during prolonged H isotope bombardment. |
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Keywords: | Swift chemical sputtering Mixed materials Ion irradiation |
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