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C_4烃在DMF中的相对挥发性
引用本文:王立新,任万忠,徐世艾,冯咏梅,徐应铨.C_4烃在DMF中的相对挥发性[J].石油化工,1997(8).
作者姓名:王立新  任万忠  徐世艾  冯咏梅  徐应铨
作者单位:烟台大学化工系
摘    要:利用静态法测定了不同温度下C4烃在DMF中的蒸气压与组成的关系曲线,与纯C4的蒸气压曲线比较,可以看出,DMF改变了正丁烷与其它C4烃之间的相对挥发性关系,这为萃取精馏法分离烷烃和烯烃提供了依据。为了验证,还测定了正丁烷和1-丁烯在DMF中的相对挥发度。

关 键 词:C_4烃  DMF  汽液平衡

Vapor Liquid Equilibrium of C 4 DMF Systems
Wang Lixin,Ren Wanzhong,Xu Shiai,Feng Yongmei and Xu Yingquan.Vapor Liquid Equilibrium of C 4 DMF Systems[J].Petrochemical Technology,1997(8).
Authors:Wang Lixin  Ren Wanzhong  Xu Shiai  Feng Yongmei and Xu Yingquan
Abstract:The P x curves of C 4 hydrocarbons dissolved in DMF was determined with a static method When the experimental data are compared with the saturated vapor curves of pure C 4 hydrocarbons,it can be shown that DMF increases the relative volatility of n butane to other C 4 hydrocarbons Therefore,it is possible that butanes and butenes can be separated by extractive distillation using DMF as extractive solvent In addition,vapor liquid equilibrium constants of n butane 1 butene DMF system were determined,and a mathematical model was established to verify the experimental data
Keywords:C  4  hydrocardons  DMF  vapor  liquid  equilibrium  
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