| 一种脱氢松香基二吡啶吩嗪衍生物的合成及其对铜离子的识别 |
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| 引用本文： | 王迎春,王恒山.一种脱氢松香基二吡啶吩嗪衍生物的合成及其对铜离子的识别[J].精细化工,2011,28(3):303-307. |
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| 作者姓名： | 王迎春 王恒山 |
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| 作者单位： | 1. 广西师范大学化学化工学院,广西桂林541004;吉首大学化学化工学院,湖南吉首416000
2. 广西师范大学化学化工学院,广西桂林,541004 |
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| 基金项目： | 国家自然科学基金，广西林产化学品开发与应用重点实验室开放基金 |
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| 摘 要： | 以脱氢松香酸甲酯为原料,经溴代、双硝化、还原、关环等步骤合成了一种脱氢松香基二吡啶吩嗪衍生物(Ⅵ),该结构通过核磁共振氢谱(1HNMR)、碳谱(13CNMR)、质谱(MS)、红外光谱及元素分析进行表征。利用荧光光谱和吸收光谱研究了在四氢呋喃溶液中其对不同金属离子的识别性能。结果表明,Ⅵ对二价铜离子具有较好的选择识别性能。
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| 关 键 词： | 脱氢松香酸甲酯 二吡啶吩嗪 吸收 荧光 铜离子识别 |
| 收稿时间： | 2010/11/3 0:00:00 |
| 修稿时间： | 2010/12/6 0:00:00 |
Synthesis of a Dehydroabietyl Dipyridophenazine Derivative and Recognition on Copper Ion |
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| WANG Ying-chun and WANG Heng-shan.Synthesis of a Dehydroabietyl Dipyridophenazine Derivative and Recognition on Copper Ion[J].Fine Chemicals,2011,28(3):303-307. |
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| Authors: | WANG Ying-chun and WANG Heng-shan |
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| Affiliation: | College of Chemistry and Chemical Engineering, Guangxi Normal University |
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| Abstract: | A dehydroabietyl dipyridophenazine derivative 6 was synthesized through several steps such as bromation, dinitration, reduction and cyclization by using methyl dehydroabietate as a starting material. The title compound was characterized by 1H NMR, 13C NMR, IR, MS and elementary analysis. Its sensing behaviors toward metal ions were investigated by UV-vis and fluorescence spectroscopy methods. The results showed that compound 6 exhibited a highly selective response to Cu2+. |
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| Keywords: | methyl dehydroabietate dipyridophenazine absorption fluorescence recognition of copper ion |
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