| KT-02负载型镍催化剂作用下合成4,4’-二氨基二苯醚的工艺研究 |
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| 引用本文： | 唐蓉萍,杨兴锴,尚秀丽,吕维华,伍家卫.KT-02负载型镍催化剂作用下合成4,4’-二氨基二苯醚的工艺研究[J].精细与专用化学品,2013(11):51-54. |
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| 作者姓名： | 唐蓉萍 杨兴锴 尚秀丽 吕维华 伍家卫 |
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| 作者单位： | [1]兰州石化职业技术学院石油化学工程系,甘肃兰州730060 [2]兰州石化职业技术学院继续教育学院,甘肃兰州730060 |
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| 基金项目： | 甘肃省省属高校基本科研业务费资助项目（甘财教2009-192） |
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| 摘 要： | 以新型工业级KT-02 Ni/SiO2为催化剂,液相催化加氢由4,4’-二硝基二苯醚(DNDPE)制备4,4’-二氨基二苯醚(DADPE),用熔点测定和FT-IR等分析测试手段鉴定了其结构。考察了温度、压力、搅拌速度及催化剂加入量等条件对加氢反应的影响,并对催化剂进行了套用实验。结果表明,以甲醇为反应介质,加入10%的KT-02镍催化剂,在90℃、2.0MPa氢压条件下反应8h,DADPE转化率大于98%,反应选择性超过97%;催化剂可至少套用8次。
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| 关 键 词： | 负载型KT-02镍催化剂 液相加氢 4 4’-二硝基二苯醚 4 4’-二氨基二苯醚 |
Synthesis of 4,4＇-diaminodiphenyl ether on KT-02 Ni/SiO2 catalyst |
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| TANG Rong-ping,YANG Xing-kai,SHANG Xiu-li,LV Wei-hua,WU Jia-wei.Synthesis of 4,4＇-diaminodiphenyl ether on KT-02 Ni/SiO2 catalyst[J].Fine and Specialty Chemicals,2013(11):51-54. |
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| Authors: | TANG Rong-ping YANG Xing-kai SHANG Xiu-li LV Wei-hua WU Jia-wei |
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| Affiliation: | 1. Department of Petrochemial Engineering , Lanzhou Petrochemical College of Vocational Technology, Lanzhou 730060, China; 2. Continuous Education College, Lanzhou Petrochemical College of Vocational Technology, Lanzhou 730060, China) |
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| Abstract: | 4, 4＇ -diaminodiphenyl ether（DADPE） was synthesized by catalyzing the hydrogenation of 4, 4＇-dinitro- diphenyl ether （DNDPE） with supported KT-02 nickel catalyst, and the structure of DADPE was identified by melting point measurement and FT-IR analyses. The effects of temperature, pressure , stir speed and the amount of catalyst on hy- drogenation reation were studied. The results show that conversion rate was up to 98% ,reaction selectivity was 97% when the amount of catalyst KT-2 was 10% ,the temperature was 90~C ,the pressure was 2. 0MPa,time was 8h. The catalyst can be used for 8 times or more. |
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| Keywords: | supported KT-02 nickel catalyst liquid hydrogenation 4 4＇-dinitrodiphenyl ether 4 4＇-diaminodi-phenyl ether |
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