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碳酸钠对细粒铝硅酸盐矿物分散行为的影响
引用本文:王毓华,陈兴华,胡业民.碳酸钠对细粒铝硅酸盐矿物分散行为的影响[J].中国矿业大学学报,2007,36(3):292-297.
作者姓名:王毓华  陈兴华  胡业民
作者单位:中南大学,资源加工与生物工程学院,湖南,长沙,410083
基金项目:国家重点基础研究发展计划(973计划)
摘    要:碳酸钠(Na2CO3)是铝土矿浮选脱硅工艺中的高效分散剂,通过沉降试验系统地研究了pH值和Na2CO3用量对一水硬铝石、高岭石、伊利石和叶腊石分散行为的影响.试验结果表明,4种单矿物在pH〈4的酸性条件下形成显著聚团,在碱性条件下则呈分散状态.其中,伊利石和叶蜡石在pH〉6,高岭石和一水硬铝石在pH〉9时处于较好分散状态.动电位测定和DLVO理论计算结果表明,添加Na2CO3后,4种单矿物的表面ζ电位的负值均显著增大,导致矿物颗粒之间的静电排斥作用增大,从而增强了4种矿物颗粒间的分散性.

关 键 词:一水硬铝石  硅酸盐  分散  ζ电位  DLVO理论
文章编号:1000-1964(2007)03-0292-06
修稿时间:08 30 2006 12:00AM

Effects of Sodium Carbonate on the Dispersion of Fine Alumin-Silicate Minerals
WANG Yu-hua,CHEN Xing-hua,HU Ye-min.Effects of Sodium Carbonate on the Dispersion of Fine Alumin-Silicate Minerals[J].Journal of China University of Mining & Technology,2007,36(3):292-297.
Authors:WANG Yu-hua  CHEN Xing-hua  HU Ye-min
Affiliation:School of Resources Processing and Bioengineering ,Central South University, Changsha, Hunan 410083, China
Abstract:Sodium carbonate(Na2CO3) is an effective dispersant for the flotation de-silicate of bauxite.Effects of pH and Na2CO3 on the dispersity of diaspore,kaolinite,illite and pyrophyllite were systematically investigated by the sedimentation experiments.The results indicate that the four minerals tended to be agglomerated in strongly-acidic solution at pH<4,but dispersed in the alkaline condition.Illite and pyrophyllite were diepersed enough at pH>6,kaolinite and diaspore were diepersed enough at pH>9.Zeta potential measurements and the DLVO theoretical calculation show that the negative zeta potentials of minerals increased with the addition of Na2CO3,the electrostatic repulsion power among mineral particles were also increased,and the dispersity of aluminum and silicate minerals were improved correspondingly.
Keywords:Na2CO3
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