| Cu(Ⅱ))的丙烯酸桥联双核配合物及醋酸、2,4,6-三甲基吡啶三元配合物的合成与表征 |
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| 引用本文： | 钱永,王建军.Cu(Ⅱ))的丙烯酸桥联双核配合物及醋酸、2,4,6-三甲基吡啶三元配合物的合成与表征[J].苏州科技学院学报(工程技术版),2012,25(1):76-80. |
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| 作者姓名： | 钱永 王建军 |
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| 作者单位： | 1. 苏州科技学院化学与生物工程学院,江苏苏州215009／江苏省环境功能材料重点实验室,江苏苏州215009
2. 苏州科技学院化学与生物工程学院,江苏苏州,215009 |
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| 基金项目： | 住房和城乡建设部科学技术项目(2011-K4-2);苏州市应用基础研究计划项目(SYG201123);环境化学与生态毒理学国家重点实验室开放基金项目(KF2010-11) |
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| 摘 要： | 在温和条件下合成了Cu(Ⅱ)的丙烯酸双核配合物Cu2(C3H3O2)4].H2O和醋酸、2,4,6-三甲基吡啶三元配合物Cu(C2H3O2)2(C8H11N)2]。通过元素分析、红外光谱、紫外光谱和核磁测试表征了该两种配合物的组成和结构,并用溶解度、电导率测试等物理化学手段对配合物的物理化学性质进行了初步研究。
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| 关 键 词： | Cu(Ⅱ) 丙烯酸 醋酸 吡啶 配合物 |
Synthesis and characterization of acrylate-bridged dinuclear copper complex and acetate and 2,4,6-trimethylpyridine copper complex |
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| QIAN Yong,WANG Jianjun.Synthesis and characterization of acrylate-bridged dinuclear copper complex and acetate and 2,4,6-trimethylpyridine copper complex[J].Journal of University of Science and Technology of Suzhou：Engineering and Technology,2012,25(1):76-80. |
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| Authors: | QIAN Yong WANG Jianjun |
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| Affiliation: | 1(1.School of Chemistry and Biological Engineering,SUST,Suzhou 215009,China;2.Jiangsu Key Laboratory of Environmental Functional Material,Suzhou 215009,China) |
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| Abstract: | The acrylate-bridged dinuclear copper complex Cu2(C3H3O2)4]·H2O and acetate and 2,4,6-Trimethylpyridine copper complex Cu(C2H3O2)2(C8H11N)2] were synthesized under tender conditions in this paper.The elemental components and structures of the two complexes were characterized and confirmed by elemental analyses,FT-IR,UV-Vis and 1H NMR.And the primary investigation on the physical and chemical characteristics of the two complexes has been carried out through some physical and chemical methods such as the solubility and molar conductivity in this work. |
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| Keywords: | Cu(Ⅱ) bridged complex crylic acid 2 4 6-Trimethylpyridin |
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