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溶聚丁苯橡胶的结构与性能
引用本文:段咏欣,赵素合,张兴英,张韬毅. 溶聚丁苯橡胶的结构与性能[J]. 橡胶工业, 2002, 49(11): 645-649
作者姓名:段咏欣  赵素合  张兴英  张韬毅
作者单位:北京化工大学,材料科学与工程学院,北京,100029
基金项目:北京市自然科学基金资助项目 (2 982 0 15 )
摘    要:研究了多官能团引发剂一步法合成的溶聚丁苯橡胶(SSBR)的结构及偶联程度对其物理性能和动态力学性能的影响,并与日本合成橡胶公司的SL552进行比较。试验结果表明,随着偶联程度的增大,SSBR的强伸性能提高,压缩疲劳温升降低,抗湿滑性提高,且偶联程度为60%的SSBR的物理性能与SL552相近。偶联程度的提高可使胶料的动态粘弹性降低。为了保证胶料达到优异的低生热特性和良好加工性能的综合平衡,偶联程度以60%为宜。

关 键 词:溶聚丁苯橡胶 结构 性能 偶联程度 物理性能 动态性能
文章编号:1000-890X(2002)11-0645-05
修稿时间:2002-05-26

Structure and properties of SSBR
DUAN Yong-xin,ZHAO Su-he,ZHANG Xing-ying and ZHANG Tao-yi. Structure and properties of SSBR[J]. China Rubber Industry, 2002, 49(11): 645-649
Authors:DUAN Yong-xin  ZHAO Su-he  ZHANG Xing-ying  ZHANG Tao-yi
Affiliation:Beijing University of Chemical Technology,Beijing University of Chemical Technology,Beijing University of Chemical Technology and Beijing University of Chemical Technology
Abstract:The influence of the structure and coupling degree for a test SSBR synthesized with one step method and multi functional initiator on the physical properties and dynamic mechanical properties of its vulcanizate was investigated by using SL552 made by JSR as control polymer.The test results showed that as the coupling degree of test SSBR increased,the tensile strength and wet traction improved and the temperature rise from compression fatigue decreased;and the SSBR with 60% coupling degree was similar to SL552 in terms of physical properties.The increase of coupling degree resulted in the decrease of dynamic visco elasticity for rubber compound.It was found that 60% coupling degree was suitable for the rubber compound to obtain the balanced low heat build up and good processibility.
Keywords:SSBR  coupling degree  physical properties  dynamic properties
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