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DNA binding and unwinding by self-assembled supramolecular hetero-bimetallacycles
Authors:Mishra Anurag  Ravikumar Sambandam  Hong Soon Ho  Kim Hyunuk  Vajpayee Vaishali  Lee Hyewoo  Ahn Byungchan  Wang Ming  Stang Peter J  Chi Ki-Whan
Affiliation:Department of Chemistry, University of Ulsan, Ulsan 680-749, Republic of Korea.
Abstract:Two new tetracationic hetero-bimetallacycles were prepared from a bis-pyridine amide ligand and metal (Pd and Pt) acceptors. We found that both self-assembled hetero-bimetallacycles bind and unwind supercoiled DNA as established by photophysical and gel electrophoresis analyses, respectively.
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