Heat and mass transfer of a multiatomic gas in a cylindrical capillary with arbitrary Knudsen numbers

Processes of heat and mass transfer of a multiatomic gas in a cylindrical channel of circular cross section with arbitrary Knudsen numbers are considered on the basis of a model kinetic equation, taking account of the excitation of rotational and vibrational degrees of freedom of the molecules.Notation Kn Knudsen number - f, f^tr total and translational Eucken factors - R_o capillary radius - m molecular mass - k Boltzmann's constant - n, T numerical density and temperature of gas - v_i i-th component of the molecular velocity - h_ij perturbation function - E_i ^(r), e_j ^(v) energy of the i-th rotational and j-th vibrational levels - E_o ^(r), E_o ^(v) equilibrium values of the rotational and vibrational energy - P_i ^(r), P_i ^(v) probability of rotational and vibrational states of energy E _i ^r and E _j ^v - , logarithmic pressure and temperature gradients - T_o mean gas temperature - R rarefaction parameter of gas - C _V ^r , C _V ^v contributions of rotational and vibrational degrees of freedom of the molecule to the specific heat at constant volume - U macroscopic gas velocity - q^(t), q^(r), q^(v) components of the heat flux density due to translational, rotational, and vibrational degrees of freedom of the molecules - P, pressure and dynamic viscosity of the gas - l free path length of molecules - up velocity of Poiseuille flow - u_T rate of thermal creep - cross-sectional area of capillary - I_n, I_q numerical and heat fluxes averaged over the channel cross section - universal index characterizing the thermomolecular pressure difference - ^t, ^r, ^v thermal conductivities due to translational, rotational, and vibrational degrees of freedom of the molecules - mass density of the gas - D_rr, D_vv diffusion coefficients of rotationally and vibrationally excited molecules among the unexcited molecules - Z_r rotational collisional number Translated from Inzhenerno-Fizicheskii Zhurnal, Vol. 47, No. 1, pp. 71–82, July, 1984.