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纳米二氧化硅改性有机硅-环氧防腐涂料的合成与性能研究
引用本文:李慧博,张秀玲.纳米二氧化硅改性有机硅-环氧防腐涂料的合成与性能研究[J].化学工程师,2011(12):60-64,69.
作者姓名:李慧博  张秀玲
作者单位:河北联合大学化工学院,河北唐山,075105
摘    要:本文利用带羟基的有机硅预聚体与双酚A型环氧树脂反应,制备有机硅-环氧树脂及涂层,并采用纳米SiO2改性有机硅-环氧.采用扫描电镜、硬度、冲击强度、附着力、柔韧性、电化学防腐特性等分析手段,考察了有机硅用量变化、纳米SiO2等对涂膜性能的影响,发现当环氧树脂有机硅用量比为2:1时,有机硅改性环氧涂层综合了有机硅树脂和环氧...

关 键 词:纳米二氧化硅  有机硅-环氧  防腐蚀涂料

Preparation and characterization of organic silicon-epoxy anti-corrosive coating modified by nanosilica
LI Hui-buo , ZHANG Xiu-ling.Preparation and characterization of organic silicon-epoxy anti-corrosive coating modified by nanosilica[J].Chemical Engineer,2011(12):60-64,69.
Authors:LI Hui-buo  ZHANG Xiu-ling
Affiliation:(College of Chemical Engineering,Hebei United University,Tangshan 075105,China)
Abstract:The organic silicon-epoxy anti-corrosive coating was prepared by organic silicon performed polymer with hydroxyl and bisphenol A type epoxy resin.The nanosilica was adopted to modify organic silicon-epoxy.The effect of amount of organic silicon and nanosilica to performance of coating was investigated by SEM,hardness,impact strength,adhesion,flexibility and electrochemical anticorrosion.It was found that when the ratio of epoxy resin and organic silicon was 2∶1,the organic silicon-epoxy anti-corrosive coating has good adhesion,resistance to aging and anticorrosive.The organic silicon-epoxy anti-corrosive coating modified by nanosilica was synthesized by adding nanosilica solution to organic silicon modified epoxy coating.Compared to organic silicon modified epoxy coating,the organic silicon-epoxy anti-corrosive coating modified by nanosilica has good uvioresistant and resistance to aging.
Keywords:nanosilica  silicone-epoxy resin  anti-corrosive coating
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