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转炉留渣双渣工艺两阶段脱磷对比
引用本文:王林珠,包燕平,李翔. 转炉留渣双渣工艺两阶段脱磷对比[J]. 钢铁, 2019, 54(8): 37-42. DOI: 10.13228/j.boyuan.issn0449 749x.20190186
作者姓名:王林珠  包燕平  李翔
作者单位:贵州大学材料与冶金学院,贵州贵阳,550025;北京科技大学钢铁冶金新技术国家重点实验室,北京,100083;贵州理工学院材料与冶金工程学院,贵州贵阳,550003
基金项目:国家自然科学基金;国家自然科学基金;贵州省科技计划
摘    要: 为了获得两阶段脱磷的关键工艺参数,通过统计100 t转炉留渣双渣工艺生产数据,比较了脱磷及脱碳阶段的脱磷有利条件,研究结果表明,两阶段脱磷条件对脱磷效果的影响规律存在显著差异,脱磷阶段炉渣碱度为1.8~2.2、Fe2O3质量分数为23%~28%、钢液温度为1 350~1 400 ℃时,可获得最优的脱磷效果;脱碳阶段炉渣碱度为3.2~5.2、Fe2O3质量分数为18%~30%、钢液温度为1 600~1 700 ℃时,提高炉渣碱度及Fe2O3质量分数或降低钢液温度可获得更优的脱磷效果;脱磷、脱碳阶段都没有达到热力学平衡,但脱磷阶段与热力学平衡差距更大,脱碳阶段更接近热力学上的平衡。

关 键 词:转炉  留渣双渣  脱磷  热力学平衡

Comparison of two stage dephosphorization during remaining #br# slag double slag process in converter
WANG Lin zhu,BAO Yan ping,LI Xiang. Comparison of two stage dephosphorization during remaining #br# slag double slag process in converter[J]. Iron & Steel, 2019, 54(8): 37-42. DOI: 10.13228/j.boyuan.issn0449 749x.20190186
Authors:WANG Lin zhu  BAO Yan ping  LI Xiang
Affiliation:(1. School of Materials and Metallurgy, Guizhou University, Guiyang 550025, Guizhou, China;2. State Key Laboratory of Advanced Metallurgy, University of Science and Technology Beijing, Beijing 100083, China;3. School of Materials and Metallurgical Engineering, Guizhou Institute of Technology, Guiyang 550003, Guizhou, China)
Abstract: In order to obtain the key process parameters of two stage dephosphorization,the production data during remaining slag double slag process for 100 t converter were collected. The favorable conditions of dephosphorization and decarburization were compared. The results show that there was a significant difference in the change rules of phosphorus removal with the changing conditions between these two stages. The optimal dephosphorization effect can be obtained in dephosphorization stage when the basicity of slag was in the range of 1.8~2.2,the mass percent of Fe2O3 was 23% 28% and molten steel temperature changed from 1 350 to 1 400 ℃. Better dephosphorization effect can be obtained by increasing the basicity of slag and Fe2O3 mass percent,or decreasing the temperature of molten steel in decarburization stage when the basicity of slag was in the range of 3.2 5.2,the mass percent of Fe2O3 was 18% 30% and the molten steel temperature changed from 1 600 to 1 700 ℃. Thermodynamic equilibrium state have not been reached during dephosphorization stage and decarbonization stage. It was further to be thermodynamic equilibrium state in dephosphorization stage but closer to that in decarbonization stage.
Keywords:converter   remaining slag double slag   dephosphorization   thermodynamic equilibrium
  
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