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Kinetic models for hydrogen sorption and their application to the H2-M system
Affiliation:1. School of Materials Science and Engineering, Jiangsu Key Laboratory of Advanced Metallic Materials, Southeast University, Nanjing 211189, China;2. Zhejiang Key Laboratory of Petrochemical Environmental Pollution Control, National Engineering Research Center for Marine Aquaculture, Marine Science and Technology College, Zhejiang Ocean University, Zhoushan 316004, China;3. ICFO-Institut de Ciències Fotòniques, The Barcelona Institute of Science and Technology, Castelldefels (Barcelona) 08860, Spain;4. Faculty of Materials and Manufacturing, Beijing University of Technology, Beijing 100124, China;5. College of Materials Science and Engineering, Jiangsu Collaborative Innovation Centre for Advanced Inorganic, Function Composites, Nanjing Tech University, Nanjing 211816, China;1. Functional Materials and Components R&D Group, Korea Institute of Industrial Technology, Gangneung 25440, Republic of Korea;2. Department of Materials Science and Engineering, Hanyang University, Seoul 04763, Republic of Korea;1. Department of Materials Science and Engineering, The University of Utah, Salt Lake City, UT 84112-0114, United States;2. State Key Laboratory of Powder Metallurgy, Central South University, Changsha, Hunan 410083, PR China;3. School of Metallurgy and Environment, Central South University, Changsha, Hunan 410083, PR China
Abstract:Several kinetic models for the H2-M system have been proposed and the corresponding rate equations developed. The solutions of these rate equations were compared to the experimental data for certain H2-metal systems. These models can successfully explain the absorption/desorption kinetics of some H2-M systems. Detailed discussions regarding the limitation of the kinetic model are also presented.
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