Abstract: | Reactions of Difluoridichloromethane with Hydrocarbons The reaction of difluordichloromethane with different hydrocarbons between 150°C and 250°C yields the CFCl2-substituted hydrocarbons. Beside it the corresponding chlorides are formed. For the hydrocarbons studied the following sequence of reactivity against difluordichloro-methane was found. n-paraffins < isoparaffins ≅ cycloparaffins < alkylaromatics < olefines. |