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Reinforcement of the mechanical properties in nitrile rubber by adding graphene oxide/silicon dioxide hybrid nanoparticles
Authors:Zhao Zhang  Xianru He  Xin Wang  Alisson M Rodrigues  Rui Zhang
Affiliation:1. State Key Laboratory of Oil and Gas Reservoir Geology and Exploitation & School of Materials Science and Engineering, Southwest Petroleum University, Chengdu 610500, People's Republic of China;2. Department of Materials Engineering, CeRTEV—Center for Research, Technology and Education in Vitreous Materials, Federal University of S?o Carlos, S?o Carlos, SP 13565‐905, Brazil;3. Institut für Physik, Universit?t Rostock, Albert‐Einstein‐Str. 23‐24, Rostock 18051, Deutschland
Abstract:Graphene oxide (GO) and silicon dioxide (SiO2) nanoparticles have been hybridized for improving the mechanical and dynamic mechanical properties of nitrile rubber (NBR). SiO2 nanoparticles were homogeneously dispersed on the surface and between layers of GO, and the new hybrid nanoparticles formed (GO/SiO2) had better thermal stability than GO. To evaluate the mechanical properties, GO/SiO2/NBR nanocomposites were prepared by solution blending and mechanical solution methods. It was observed that tensile strength increased in a larger grade in GO/SiO2/NBR nanocomposites than that in GO/NBR and SiO2/NBR nanocomposites, while the elongation at break only changes smoothly. Moreover, dynamics measurements also indicated that the elasticity increased after adding GO/SiO2 hybrid nanoparticles in NBR. From morphology's analysis of GO/SiO2/NBR and GO/NBR nanocomposites, it is was conclude that the hybridization of the GO/SiO2 was the determining factor for the reinforcement of the mechanical properties and elasticity of the NBR. © 2017 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2018 , 135, 46091.
Keywords:graphene and fullerenes  mechanical properties  nanotubes  rubber
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