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Surface Modification of Alumina/ Zirconia Ceramics Upon Different Fluoride‐Based Treatments
Authors:Simona Cavalu  Florin Banica  Viorica Simon  Ipek Akin  Gultekin Goller
Affiliation:1. Faculty of Medicine and Pharmacy, University of Oradea, , Oradea, Romania;2. Faculty of Physics & Institute of Interdisciplinary Research in Bio‐Nano‐Sciences, Babes‐Bolyai University, , Cluj‐Napoca, Romania;3. Metallurgical & Materials Engineering Department, Istanbul Technical University, , Istanbul, Turkey
Abstract:The aim of this study was to prepare and to characterize the structure of Al2O3–3YSZ composites with 5% TiO2 addition as well as the surface modification upon treatments with SnF2 and NaBF4, respectively. SEM micrographs showed the controlled densification of the composites as an effect of 3YSZ and TiO2 addition to alumina matrix. By FTIR and XRD, the characteristics of Al‐O and Zr‐O vibrations, respectively, the diffractions lines related to α‐corundum and zirconia in tetragonal phase were discussed. Qualitative and quantitative results obtained by XPS and ATR FTIR demonstrated that the proposed materials are more sensitive to SnF2 than to NaBF4 treatment.
Keywords:
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