| 电沉积Ni—Mo—P—SiC复合镀层的热力学分析 |
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| 引用本文： | 朱晓云.电沉积Ni—Mo—P—SiC复合镀层的热力学分析[J].云南化工,1999(4):1-3. |
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| 作者姓名： | 朱晓云 |
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| 作者单位： | 昆明贵金属研究所!中国昆明650221 |
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| 摘 要： | 计算并绘制了Ｎｉ－ Ｐ－ Ｈ２Ｏ系电位－ ｐＨ图，从热力学角度分析了电沉积Ｎｉ－ Ｍｏ－ Ｐ－ ＳｉＣ复合镀层的机理。结果表明，磷不能单独从水溶液中沉积出来，但它可以与镍以Ｎｉ３Ｐ的形式实现共沉积。
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| 关 键 词： | Ni-Mo-P-SiC复合镀层 热力学 机理 |
Thermodynamic Analysis of Electrodeposited Ni-Mo-P-SiC Composite Coating |
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| ZHU Xiao-yun.Thermodynamic Analysis of Electrodeposited Ni-Mo-P-SiC Composite Coating[J].Yunnan Chemical Technology,1999(4):1-3. |
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| Authors: | ZHU Xiao-yun |
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| Abstract: | The voltage-pH diagram of Ni-P-H 2O system in 298K standard condition was plotted by means of dependable thermodynamic data.The mechanism of electrodeposition Ni-Mo-P-SiC composite coating was analyzed with respect to thermodynamics.The results showed that phosphorus could not be co-deposited in solution.However,it could be co-deposited with nickel in type of Ni 3P. |
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| Keywords: | Ni-Mo-P-SiC composite coating thermodynamics mechanism |
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