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Direct synthesis of PbS/polypyrrole core-shell nanocomposites based on octahedral PbS nanocrystals colloid
Authors:Shengyu Jing  Chun Zhao
Affiliation:a State Key Laboratory on Integrated Optoelectronics, Jilin University, Changchun 130012, People's Republic of China
b College of Chemistry, Jilin University, Changchun 130012, People's Republic of China
Abstract:PbS/polypyrrole core-shell nanocomposites were successfully synthesized via in situ chemical oxidation polymerization of pyrrole based on the octahedral PbS nanocrystals colloid. Transmission electron microscopy (TEM) showed that the PbS nanocrystals are as the cores of the nanocomposites and the polypyrrole wrap the octahedral PbS nanocrystals as the shell. X-ray diffraction (XRD), Fourier transform infrared (FTIR) spectra and UV-Vis spectra were used to characterize the structure of the obtained PbS/polypyrrole nanocomposites. A possible formation mechanism of the PbS/polypyrrole core-shell nanocomposites was also proposed.
Keywords:Core-shell nanocomposites  Polypyrrole  Octahedral PbS nanocrystals colloid
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