Improved synthesis of sucrose fatty acid monoesters |
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Authors: | M Angeles Cruces Francisco J Plou Manuel Ferrer Manuel Bernabé Antonio Ballesteros |
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Affiliation: | (1) Departamento de Biocatálisis, Instituto de Catálisis, C.S.I.C., Cantoblanco, 28049 Madrid, Spain;(2) Instituto de Química Orgánica, C.S.I.C., 28006 Madrid, Spain |
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Abstract: | The base-catalyzed synthesis of four sucrose fatty acid esters (caprylate, laurate, myristate, and palmitate) was performed
in dimethylsulfoxide by transesterification of sucrose with the corresponding vinyl esters using disodium hydrogen phosphate
as catalyst. In using a molar ratio sucrose/vinyl ester 4∶1 and mild reaction conditions (40°C and atmospheric pressure),
yields were higher than 85%. The isolated sucroesters had a higher percentage of monoesters (≥90%) and a lower content of
diesters in comparison with commercial derivatives. In all cases, 2-O-acylsucrose was the major product (≥60%) in the monoester fraction. |
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Keywords: | Acylation fatty acid ester nonionic surfactant organic solvents sucrose monoester transesterification vinyl ester |
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