| 尼龙-6膜与丙烯酸接枝共聚合的研究 |
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| 引用本文： | 刘民英,王玉东,牛俊峰,徐卫河,赵清香,李相魁.尼龙-6膜与丙烯酸接枝共聚合的研究[J].高分子材料科学与工程,2001,17(4):52-56. |
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| 作者姓名： | 刘民英 王玉东 牛俊峰 徐卫河 赵清香 李相魁 |
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| 作者单位： | 1. 郑州大学材料工程系,
2. 郑州粮食学院化学化工系, |
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| 基金项目： | 河南省自然科学基金资助项目 |
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| 摘 要： | 通过一系列实验选择以（NH4）2（NO）6／HSO4为引发剂，了尼龙－6膜与丙烯酸的接枝共聚合反应，通过改变单体浓度，反应温度，（NH4）2Ce(NO3)6浓度，H2SO4浓度，尼龙－6膜在甲酸中的溶胀时间等因素发现，接枝膜的接枝率与单体浓度有关，。随单体浓度的改变，接枝率有一个极大值，单体浓度高于或低于此浓度，接枝率都较低，通过改变（NH4）2Ce(NO3)6和H2SO4浓度也得到类似规律，反应温度对接枝膜的接枝率也有影响，温度过高（＞70度）或过低（小于40℃）都得不到较高的接枝率；将尼龙－6膜在20％甲酸中溶胀，有利于提高产物的接枝率。
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| 关 键 词： | 尼龙－6膜 丙烯酸 接枝共聚合 单体浓度 反应温度 |
| 文章编号： | 1000-7555(2001)04-0052-05 |
STUDIES ON GRAFTING COPOLYMERIZATION OF NYLON-6 MEMBRANE WITH ACRYLIC ACID |
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| LIU Min ying,WANG Yu dong,NIU Jun feng,ZHAO Qin xiang,LI Xiang kui.STUDIES ON GRAFTING COPOLYMERIZATION OF NYLON-6 MEMBRANE WITH ACRYLIC ACID[J].Polymer Materials Science & Engineering,2001,17(4):52-56. |
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| Authors: | LIU Min ying WANG Yu dong NIU Jun feng ZHAO Qin xiang LI Xiang kui |
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| Abstract: | Grafting polymerization of nylon 6 membrane with acrylic acid initiated by a (NH 4) 2Ce(NO 3) 6/H 2SO 4 mixture was extensively studied. The grafting reaction were influenced by the temperature and time of the reaction, concentrations of (NH 4) 2Ce(NO 3) 6 and H 2SO 4, and time of nylon 6 membrane swelled in 20% formic acid. It was found that there are optimal concentrations of acrylic acid, (NH 4) 2Ce(NO 3) 6 and H 2SO 4, below or above these concentrations, lower grafting occurs. Temperature was also a factor that affects the grafting yield. Swelled nylon 6 membrane in 20% formic acid is favorable to grafting yield. |
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| Keywords: | nylon 6 acrylic acid graft membrane grafting polymerizatio |
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