| N-甲基-4-氨基邻苯二甲酰亚胺的合成研究 |
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| 引用本文： | 张亚男,唐有根,肖方明,朱鹤专.N-甲基-4-氨基邻苯二甲酰亚胺的合成研究[J].广州化工,2009,37(8):111-112,115. |
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| 作者姓名： | 张亚男 唐有根 肖方明 朱鹤专 |
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| 作者单位： | 中南大学化学化工学院;广州有色金属研究院稀有金属研究所; |
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| 摘 要： | 以4-硝基-邻苯二甲酰亚胺为原料，碳酸二甲酯作为甲基化试剂制备N-甲基-4-硝基邻苯二甲酰亚胺，优化各反应条件，收率达78％；再经铁粉还原制备N-甲基-4-氨基邻苯二甲酰亚胺，优化各反应条件，收率达91．5％。
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| 关 键 词： | N-甲基-4-氨基邻苯二甲酰亚胺 N-甲基-4-硝基邻苯二甲酰亚胺 碳酸二甲酯 |
Study on Synthesis of N-methyl-4-aminophthalimide |
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| ZHANG Ya-nan,TANG You-gen,XIAO Fang-ming,ZHU He-zhuan.Study on Synthesis of N-methyl-4-aminophthalimide[J].GuangZhou Chemical Industry and Technology,2009,37(8):111-112,115. |
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| Authors: | ZHANG Ya-nan TANG You-gen XIAO Fang-ming ZHU He-zhuan |
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| Affiliation: | 1 College of Chemistry and Chemical Engineering;Central South University;Hunan Changsha 410083;2 Research Institute of Rare Metal;Guangzhou Research Institute of Non-ferrous Metals;Guangdong Guangzhou 510651;China |
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| Abstract: | N-methyl-4-nitrophthalimide was synthesized from 4-nitrophthalimide and dimethylcarbonate.After the reaction condition was optimized,the yeild of N-methyl-4-nitrophthalimide reached 78%.Then,N-methyl-4-nitrophthalimide was reduced by Fe powder.After the reaction condition was optimized,the yeild of N-methyl-4-aminophthalimide reached 78%. |
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| Keywords: | N-methyl-4-aminophthalimide N-methyl-4-nitrophthalimide dimethylcarbonate |
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