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新型蒽醌加氢催化剂的制备及加氢性能研究
引用本文:张建国,李德伏,赵玉军,孔庆单,王树东.新型蒽醌加氢催化剂的制备及加氢性能研究[J].工业催化,2008,16(2):62-65.
作者姓名:张建国  李德伏  赵玉军  孔庆单  王树东
作者单位:1.中国科学院大连化学物理研究所, 辽宁 大连 116023; 2.中国科学院研究生院, 北京 100049
摘    要:在蒽醌法生产过氧化氢中,采用蝶形氧化铝载体,通过控制贵金属浸渍条件,制备出蛋壳分布的新型钯催化剂。催化剂贵金属负载量低,活性组分浸渍层薄,催化剂活性高及反应稳定性好。实验室和工业模式评价实验表明,制备的催化剂表现出良好的活性及稳定性,其时空产率为工业用催化剂的1.5倍以上。

关 键 词:催化剂工程  过氧化氢  钯催化剂  蒽醌加氢  
文章编号:1008-1143(2008)02-0062-04
修稿时间:2007年9月5日

Investigation of anthraquinone hydrogenation over a new catalyst
ZHANG Jianguo,LI Defu,ZHAO Yujun,KONG Qingdan,WANG Shudong.Investigation of anthraquinone hydrogenation over a new catalyst[J].Industrial Catalysis,2008,16(2):62-65.
Authors:ZHANG Jianguo  LI Defu  ZHAO Yujun  KONG Qingdan  WANG Shudong
Affiliation:1.Dalian Institute of chemical physics, Chinese Academy of Sciences, Dalian 116023, Liaoning,China; 2.Graduate School of Chinese Academy of Sciences, Beijing 100039, China
Abstract:A novel anthraquinone hydrogenation catalyst for hydrogen peroxide production was prepared with papilionaceous alumina carrier by impregnation method. The catalyst had low Pd loading and thin active layer. High catalytic activity and stability were obtained in the anthraquinone hydrogenation process in the lab test and pilot experiments. The space time yield over the catalyst was as 1.5 times as that over commercial catalysts.
Keywords:hydrogen peroxide  Pd catalyst  anthraquinone hydrogenation  catalyst engineering  
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