| 正庚烷-甲苯-三甘醇三元体系液-液相平衡数据的测定与关联 |
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| 引用本文： | 靳广洲,高俊斌,丁福臣,郁浩然. 正庚烷-甲苯-三甘醇三元体系液-液相平衡数据的测定与关联[J]. 石油化工, 1998, 0(10) |
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| 作者姓名： | 靳广洲 高俊斌 丁福臣 郁浩然 |
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| 作者单位： | 北京石油化工学院化工系 |
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| 摘 要： | 利用气相色谱法测定了常压下２５℃、４０℃和５０℃时正庚烷－甲苯－三甘醇体系的液－液相平衡数据，采用峰面积归一化法定量，所得数据准确、可靠。用ＮＲＴＬ模型对所测数据进行了热力学关联，求出了相应的模型参数。用该模型对本三元体系进行了预测，结果令人满意。
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| 关 键 词： | 三甘醇 甲苯 正庚烷 液液平衡 关联 预测 |
Determination and Correlation of Liquid Liquid Equilibrium Data for the Ternary System of Toluene n Heptane Triethylene Glycol |
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| Jin Guangzhou,Gao Junbin,Ding Fuchen and Yu Haoran. Determination and Correlation of Liquid Liquid Equilibrium Data for the Ternary System of Toluene n Heptane Triethylene Glycol[J]. Petrochemical Technology, 1998, 0(10) |
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| Authors: | Jin Guangzhou Gao Junbin Ding Fuchen Yu Haoran |
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| Abstract: | Liquid liquid equilibrium(LLE) data of toluene n heptane triethylene glycol of ternary system at 25 ℃,40 ℃ and 50 ℃ are determined under atmospheric pressure by gas chromatography The quantitative analysis is based on the normalization of peak area %,and accurate results are obtained The NRTL model is used to correlate and predict the LLE data of the system and to obtain the models parameters at 25 ℃,40 ℃ and 50 ℃ The agreement between calculated and experimental data is satisfactory |
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| Keywords: | triethylene glycol toluene n heptane liquid liquid equilibrium correlation prediction |
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