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淡水中镁基牺牲阳极上的析氢行为
引用本文:曾爱平 张承典. 淡水中镁基牺牲阳极上的析氢行为[J]. 中国腐蚀与防护学报, 1999, 19(2): 85-89
作者姓名:曾爱平 张承典
作者单位:中国科学院上海冶金研究所!上海200050
摘    要:用失重法,收集氢气,电子探针合金成分分析和腐蚀形貌观察等方法。研究了AZ63和ZA41镁合金及纯镁在水中的析氢行为,结果表明:在淡水中镁阳极处于活性溶解状态;淡水中镁阳极上的析氢速度与电流密度呈线性关系,这与在0.5mol/LNaCl+Mg(OH)2(pH=10.2)溶液中的情况类似。

关 键 词:镁基牺牲阳极 淡水 析氢 腐蚀

HYDROGEN EVOLUTION ON MAGNESIUM SACRIFICIAL ANODE IN FRESH WATER
ZENG Ai-ping, ZHANG Chen-dian, XU Nai-xin. HYDROGEN EVOLUTION ON MAGNESIUM SACRIFICIAL ANODE IN FRESH WATER[J]. Journal of Chinese Society For Corrosion and Protection, 1999, 19(2): 85-89
Authors:ZENG Ai-ping   ZHANG Chen-dian   XU Nai-xin
Abstract:Hydrogen evolution on three sacrifical magnesium anodes AZ63, AZ41 and pure magnesium in freshwater has been studied by means of weight loss, hydrogen collection, electron probe analysis and morpho-logical observation. The results show that all the three magnesium anodes in fresh water are in active stateand the velocity of hydrogen evolution is linearly dependent on current density Their negative differentialeffect coefficients in fresh water are less than that for magnesium in 0.5mol/L NaCl Mg(OH)2(pH10.2)solution. Hence the hydrogen evolution is not the only reason for the low current efficiency of magnesiumanodes. The fall of magnesium grains may be the another important canse.
Keywords:Magnesium sacrificial anode   Fresh water   Hydrogen evolution
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