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Influences of clay and manufacturing on fire resistance of organoclay/thermoset nanocomposites
Affiliation:1. Department of Infrastructure Engineering, The University of Melbourne, Australia;2. Centre for Advanced Composite Materials, The University of Auckland, New Zealand;1. Department of Bionanosystem Engineering, Graduate School, Chonbuk National University, 567 Baekje-daero, Deokjin-gu, Jeonju-si, Jeollabuk-do 54896, Republic of Korea;2. Division of Mechanical Design Engineering, Chonbuk National University, 567 Baekje-daero, Deokjin-gu, Jeonju-si, Jeollabuk-do 54896, Republic of Korea;1. Research and Development Centre, Bharathiar University, Coimbatore 641046, Tamilnadu, India;2. Department of chemistry, Government arts college, Kumbakonam, Tamilnadu, India;1. Dr. Senckenberg Institute of Pathology, Goethe University, Frankfurt am Main, Germany;2. Department of Experimental, Diagnostic and Specialty Medicine, Haematopathology Section, S. Orsola-Malpighi Hospital, University of Bologna, Bologna, Italy;3. Pathology Unit, Department of Molecular and Translational Medicine, University of Brescia, Italy;4. Hematopathology Section, Hospital Clinic, IDIBAPS, University of Barcelona, Barcelona, Spain;5. Histopathology, SRL Diagnostics, Mumbai 400013, India;6. Immunology, Gießen University Hospital, Gießen, Germany;7. Department of Dermatology, Goethe University, Frankfurt am Main, Germany;8. Institute of Pathology, Medical University of Vienna, Vienna, Austria;9. Department of Pathology, Portuguese Institute of Oncology, Lisbon, Portugal;10. Unit of Diagnostic Haematopathology, European Institute of Oncology, Milan, Italy;1. College of Materials Science and Engineering, Fuzhou University, Fuzhou 350116, PR China;2. College of Printing and Packing Engineering, Xi’an University of Technology, Xian 710048, PR China;1. Department of Statistical Sciences, University of Toronto, Toronto, Ontario M5S 3G3, Canada;2. Département de mathématiques et de statistique, Université Laval, Québec City, Québec G1V 0A6, Canada
Abstract:The organoclay GFRP nanocomposites are prepared using the vacuum assisted resin transfer moulding method. Two grades of organophilic clay with three content levels, three types of thermosetting resins (polyester, vinyl ester and epoxy), and three nanoclay dispersion techniques are investigated. To understand the effects of these factors on the fire performance, Taguchi design of experiments (DoE) method is employed and preferred combinations of factors are determined using a one-step and a proposed two-step GLM ANOVA. The one-step ANOVA is applied directly on the experimental results, while the two-step ANOVA is conducted on the signal-to-noise ratios obtained from the Taguchi analysis. The combination of mechanical and ultrasonic dispersing procedure has been found to have considerable influence on the of nanoclay distribution. While both approaches provide insights into the influences of each fabrication factor, the two-step gives a better prediction of the favourable response combination for the nanocomposites when validated with experiments.
Keywords:A. Nano-structures  A. Polymer matrix composites (PMCs)  B. Thermal properties  C. Statistical properties/methods
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