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Transparent and flexible cellulose nanofibers/silver nanowires/acrylic resin composite electrode
Affiliation:1. Division of Pharmaceutical Biosciences, Faculty of Pharmacy, University of Helsinki, P.O. Box 56, FI-00014 Helsinki, Finland;2. VTT Technical Research Centre of Finland, P.O. Box 1000, FI-02044 VTT Espoo, Finland;3. Department of Pharmaceutical and Pharmacological Sciences, via Marzalo 5, University of Padova, Padova, Italy;4. Department of Chemistry and Bioengineering, Tampere University of Technology, P.O. Box 541, FI-33101 Tampere, Finland;1. Institute of Industrial Chemistry and Energy Technology, Shenyang University of Chemical Technology, Shenyang 110142, PR China;2. Yunnan Province Key Lab of Wood Adhesives and Glued Products, Kunming 650224, PR China;3. Key Laboratory of Bio-based Material Science and Technology of Ministry of Education, Northeast Forestry University, Harbin 150040, PR China
Abstract:In this study, we report a novel, eco-friendly and simple method to fabricate cellulose nanofibers (CNFs)/silver nanowires (AgNWs)/acrylic resin (AR) composite electrode. CNFs with average diameter of 15 nm were disintegrated only by one time-pass grinding. Aqueous dispersion of AgNWs was embedded onto the surface of CNFs film by simple vacuum filtration. The final composite electrode was obtained by impregnating CNFs/AgNWs film to AR with the assist of adhesive tape. This electrode with AgNWs density of 134 mg/m2 showed low sheet resistance (4 Ω/sq), and high light transmittance (85%) which was 6% lower than that of neat AR. The coefficient of thermal expansion of the composite electrode was as low as 25.32 ppm K−1. The tensile strength and Young’s modulus of CNFs/AgNWs/AR composite film were 35.71 MPa and 1.63 GPa, which were about 8 and 5.8 times larger than neat AR film, respectively.
Keywords:A. Nano-structures  A. Thin films  B. Optical properties/techniques  D. Physical methods of analysis
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