| Mo-Ni-P纳米自组装Al2O3劣质柴油加氢催化剂脱硫研究 |
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| 引用本文： | 张国伟,赵德智,王鼎聪,石薇薇,丁薇,宋官龙,侯丹丹.Mo-Ni-P纳米自组装Al2O3劣质柴油加氢催化剂脱硫研究[J].石油化工高等学校学报,2011(4):37-40. |
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| 作者姓名： | 张国伟 赵德智 王鼎聪 石薇薇 丁薇 宋官龙 侯丹丹 |
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| 作者单位： | 辽宁石油化工大学石油化工学院;抚顺石油化工研究院; |
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| 基金项目： | 中国石油化工集团公司资助项目(030801) |
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| 摘 要： | 制备了以纳米自组装大孔容介孔氧化铝为载体,改性和共浸法制备担载Mo-Ni双金属活性组分的Mo-Ni-P纳米自组装Al2O3柴油加氢脱硫催化剂。通过压汞法和XRD对催化剂进行表征。纳米自组装大孔容介孔氧化铝催化剂Ni-Mo的负载量为w（NiO）=7.69%,w（MoO3）=27.2%,P改性后其质量分数为0.05%。以孤岛焦化柴油为原料,在固定床反应器上评价了催化剂的脱硫反应活性。结果表明,脱硫适宜的反应条件为：反应温度370℃,压力7.5 MPa,氢油体积比700,体积空速1.5 h-1。在此条件下,柴油含硫质量分数可由14 100μg/g降至125μg/g。
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| 关 键 词： | 纳米自组装Al2O3 加氢精制 脱硫 催化剂 Ni-Mo-P |
Mo-Ni-P Self-Assembled Nano-Al_2O_3 Hydrodesulfurization of Diesel Catalysts |
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| ZHANG Guo-wei,ZHAO De-zhi,WANG Ding-cong,SHI Wei-wei,DING Wei,SONG Guan-long,HOU Dan-dan.Mo-Ni-P Self-Assembled Nano-Al_2O_3 Hydrodesulfurization of Diesel Catalysts[J].Journal of Petrochemical Universities,2011(4):37-40. |
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| Authors: | ZHANG Guo-wei ZHAO De-zhi WANG Ding-cong SHI Wei-wei DING Wei SONG Guan-long HOU Dan-dan |
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| Affiliation: | ZHANG Guo-wei1,ZHAO De-zhi1,WANG Ding-cong2,SHI Wei-wei1,DING Wei1,SONG Guan-long1,HOU Dan-dan1(1.College of Petrochemical Technology,Liaoning Shihua University,Fushun Liaoning 113001,P.R.China,2.Fushun Research Institute of Petroleum and Petrochemicals,P.R.China) |
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| Abstract: | Mo-Ni-P self-assembled nano-Al2O3 catalyst for hydrodesulfurization of diesel can be prepared,Mo-Ni bimetallic active component was supported on the large pore volume of nano self-assembly of mesoporous alumina by the method of modification and immersion.The catalysts is characterized by mercury and XRD.The loading of Mo-Ni bimetallic in large pore volume of nano self-assembly of mesoporous Ni-Mo alumina catalyst is w(NiO)=7.69%,w(MoO3)=27.2%,w(P)=0.05%.The active of catalyst,the fixed bed reactor and Gudao... |
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| Keywords: | Self-assembly nano-Al2O3 Hydrotreating Desulfurization Catalyst Ni-Mo-P |
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