| 可聚合8-羟基喹啉衍生物的合成及高分子化 |
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| 引用本文： | 胡芬,刘承美,雷国夫. 可聚合8-羟基喹啉衍生物的合成及高分子化[J]. 高分子材料科学与工程, 2006, 22(2): 100-103 |
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| 作者姓名： | 胡芬 刘承美 雷国夫 |
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| 作者单位： | 华中科技大学化学系,湖北,武汉,430074;华中科技大学化学系,湖北,武汉,430074;华中科技大学化学系,湖北,武汉,430074 |
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| 摘 要： | 5氯-甲基-8-羟基喹啉与烯丙醇反应,得到5-(烯丙氧)甲基-8-羟基喹啉可聚合单体,进一步与苯乙烯聚合,得到含8羟-基喹啉基团的高分子。将所得的聚合物与铝离子配位得到高分子配合物(最大发射波长为512 nm)。利用红外光谱、紫外光谱、核磁共振和原子力显微镜(AFM)对配体和配合物的结构进行了表征,利用荧光光谱研究了配合物的光致发光性能。
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| 关 键 词： | 高分子配合物 8-羟基喹啉 光致发光 |
| 文章编号： | 1000-7555（2006）02-0100-04 |
| 收稿时间： | 2004-12-21 |
| 修稿时间： | 2005-04-26 |
PREPARATION AND PHOTOLUMINESCENT PROPERTY OF POLYMERIC 8-HYDROXYQUINOLINE ALUMINUM COMPLEX |
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| HU Fen,LIU Cheng-mei,LEI Guo-fu. PREPARATION AND PHOTOLUMINESCENT PROPERTY OF POLYMERIC 8-HYDROXYQUINOLINE ALUMINUM COMPLEX[J]. Polymer Materials Science & Engineering, 2006, 22(2): 100-103 |
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| Authors: | HU Fen LIU Cheng-mei LEI Guo-fu |
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| Affiliation: | Department of Chemistry, Huazhong University of Science and Technology, Wuhan 430074, China |
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| Abstract: | 5-allyloxymethyl-8-hydroxyquinoline was prepared by reaction between 5-chloromethyl-8-hydroxyquinoline and allylethanol.This monomer was copolymerized with styrene to prepare a polymer contaning 8-hydroxyqunoline side group.Then the polymer was coordinated with aluminum ion to prepare the polymeric complexes.The chemical structure and properties of ligand and polymeric complexes were studied by FT-IR,UV-Vis,NMR and AFM.The results indicate that polymeric complexes have excellent photoluminescent properties with maximum mission wavelength around 510 nm. |
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| Keywords: | polymeric complex 8-hydroxy-quinoline photoluminescence |
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