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硅和锡对ZA27锌基合金耐腐蚀性能的影响
引用本文:李逸泰,范鹏,宋亮,庞兴志,曾建民.硅和锡对ZA27锌基合金耐腐蚀性能的影响[J].机械工程材料,2006,30(12):27-28,94.
作者姓名:李逸泰  范鹏  宋亮  庞兴志  曾建民
作者单位:广西大学有色金属及材料加工新技术教育部重点实验室,广西,南宁,530004
摘    要:在35g/LNaCl水溶液中,用电化学测量系统测定了硅加入量分别为0.11%,0.19%,0.30%和锡加入量分别为0.10%,0.15%,0.21%,0.26%的ZA27锌基合金的塔菲尔曲线、腐蚀电位、线性极化电阻和腐蚀电流密度等电化学参数,在扫描电镜下观察了腐蚀后的形貌,并与二元ZA27合金进行了比较。结果表明:硅和锡的加入使试验合金的腐蚀电位朝负向移动,腐蚀电流密度增加,均降低了ZA27高铝锌基合金的耐腐蚀性能,其中锡的影响较大.

关 键 词:ZA27锌基合金  耐腐蚀性能  腐蚀电位
文章编号:1000-3738(2006)12-0027-02
收稿时间:2006-01-25
修稿时间:2006-01-252006-11-03

Effects of Si and Sn on Corrosion Resistance of ZA27 Alloy
LI Yi-tai,FAN Peng,SONG Liang,PANG Xing-zhi,ZENG Jian-min.Effects of Si and Sn on Corrosion Resistance of ZA27 Alloy[J].Materials For Mechanical Engineering,2006,30(12):27-28,94.
Authors:LI Yi-tai  FAN Peng  SONG Liang  PANG Xing-zhi  ZENG Jian-min
Affiliation:Guangxi University, Nanning 530004, China
Abstract:The Tafel curves and electrochemical parameters such as free corrosion potential, resistance of linear polarization, corrosion current density of ZA27 alloys which contains 0. 11%, 0. 19%, 0. 30%Si, 0. 10%, 0. 15%, 0. 21%, 0. 26%Sn respectively, have been measured by using PS-168C electrochemistry measurement system in 35 g/L NaCl solution. The surface morphology of the samples after corrosion test was observed by SEM. Compared with the experimental result of ZA27 alloy, it is shown that the free corrosion potential of all the tested alloys shifts to negative and the their corrosion current densities increase with impurity elements addition. And impurity elements decrease corrosion resistance of ZA27 alloy. The ef fect of Sn is greater than that of Si.
Keywords:Al-Zn alloy  corrosion resistance  free corrosion potential
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