| 聚酰胺表面改性三聚氰胺氰尿酸盐及其阻燃聚酰胺6研究 |
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| 引用本文： | 费国霞,刘渊,王琪,汤洪梅.聚酰胺表面改性三聚氰胺氰尿酸盐及其阻燃聚酰胺6研究[J].中国塑料,2005,19(10):44-47. |
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| 作者姓名： | 费国霞 刘渊 王琪 汤洪梅 |
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| 作者单位： | 高分子材料工程国家重点实验室四川大学高分子研究所，高分子材料工程国家重点实验室四川大学高分子研究所，高分子材料工程国家重点实验室四川大学高分子研究所，高分子材料工程国家重点实验室四川大学高分子研究所 四川 成都 610065，四川 成都 610065，四川 成都 610065，四川 成都 610065 |
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| 基金项目： | 国家高技术研究发展计划(863项目)——高性能低成本工程塑料制备新技术(2002AAA333070)资助项目 |
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| 摘 要： | 以聚酰胺树脂的无机酸溶液为介质进行三聚氰胺-氰尿酸分子自组装合成三聚氰胺氰尿酸盐(MCA),并同时实现聚酰胺树脂对阻燃剂的表面包覆改性,集MCA的合成及表面改性于一体。该阻燃剂与目标阻燃树脂聚酰胺6 的相容性良好,阻燃剂粒子与聚酰胺6(PA6)树脂基体之间相界面基本消失。聚酰胺6中添加7％该阻燃剂即达到 UL94-1．6mm V0级别,成功解决了传统MCA阻燃PA6燃烧熔滴易引燃脱脂棉的问题,其极限氧指数高达34％,阻燃效率远高于传统MCA。材料力学性能良好,具有较好的市场应用前景。
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| 关 键 词： | 三聚氰胺氰尿酸盐 阻燃剂 表面改性 聚酰胺6 |
| 文章编号： | 1001-9278（2005）10-0044-04 |
| 收稿时间： | 2005-07-12 |
| 修稿时间： | 2005-07-12 |
Melamine Cyanurate with Surface Modified by Polyamide Resin and Its Flame Retardancy on Polyamide 6 |
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| FEI Guo-xia, LIU Yuan, WANG Qi , TANG Hong-mei.Melamine Cyanurate with Surface Modified by Polyamide Resin and Its Flame Retardancy on Polyamide 6[J].China Plastics,2005,19(10):44-47. |
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| Authors: | FEI Guo-xia LIU Yuan WANG Qi TANG Hong-mei |
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| Affiliation: | State Key Laboratory of Polymer Materials Engineering, Polymer Research Institute of Sichuan University, Chengdu 610065, China |
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| Abstract: | Melamine cyanurate (MCA) is an important nitrogen-containing flame retardant, particularly suitable for PA. However, the poor dispersion of MCA in PA matrix may result in a low flame retardan-cy. The extinguish time was long and the melt-drip of PA6 may ignite the absorbent cotton. In this paper, a self-assembled melamine-cyanurate was prepared in an inorganic acid solution of polyamide 6 and was simultaneously encapsulated with polyamide 6. The modified MCA had good compatibility with PA6 and enhanced the flame retardancy. PA6 samples containing 7 % modified MCA achieved a limiting oxygen index (LOI) of 34 % and an UL94-1.6 mm V0 rating. The melting dripping no longer ignited the absorbent cotton during the UL-94 flame test. The tensile and Izod notched impact strength of the sample were 61.3 MPa and 4.0 kJ/m2, respectively. |
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| Keywords: | melamine cyanurate flame retardant surface modification polyamide 6 |
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