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葵花籽壳对溶液中铀酰离子的吸附
引用本文:王长福,刘峙嵘,薛桂荣,赖毅,王云,周利民.葵花籽壳对溶液中铀酰离子的吸附[J].核化学与放射化学,2016,38(2):107-115.
作者姓名:王长福  刘峙嵘  薛桂荣  赖毅  王云  周利民
作者单位:东华理工大学 化学生物与材料科学学院,江西 南昌330013
基金项目:国家自然科学基金资助项目(11375043),江西省科技支撑计划资助项目(20133BBF60016
摘    要:选取农业副产物葵花籽壳作为吸附剂,研究其对溶液中铀酰离子的吸附性能。用元素分析、扫描电镜、红外光谱分析等方法对吸附铀前后的葵花籽壳进行分析和表征,通过静态实验分别研究了时间、温度、pH值、铀酰离子初始浓度、葵花籽壳用量等因素对吸附效果的影响。结果表明:吸附的适宜pH为5.0~6.0,35℃下,当铀溶液初始质量浓度为50mg/L,溶液pH=5.0,葵花籽壳质量浓度为1.00g/L时,饱和吸附量可达29.2mg/g。

关 键 词:葵花籽壳    吸附  

Adsorptive Properties of Sunflower Seed Shells for UO22+ in Aqueous Solution
WANG Chang-fu,LIU Zhi-rong,XUE Gui-rong,LAI Yi,WANG Yun,ZHOU Li-min.Adsorptive Properties of Sunflower Seed Shells for UO22+ in Aqueous Solution[J].Journal of Nuclear and Radiochemistry,2016,38(2):107-115.
Authors:WANG Chang-fu  LIU Zhi-rong  XUE Gui-rong  LAI Yi  WANG Yun  ZHOU Li-min
Affiliation:College of Chemical, Biological and Material Science, East China Institute of Technology, Nanchang 330013, China
Abstract:Adsorption characteristics of sunflower seed shells have been studied for U(Ⅵ) removal from aqueous solution. The sunflower seed shells were characterized by elemental analysis, scanning electron microscopy, and FT-IR. Adsorption of U(Ⅵ) from aqueous solution by means of sunflower seed shells was studied in a series of batch experiments. The adsorption behavior of U(Ⅵ) onto the adsorbent was investigated as function of pH value, contact time, initial U(Ⅵ) concentration, temperature etc. The results show that the adsorption capacity is 29.2 mg/g at the pH=5.0 and 35 ℃ with initial U(Ⅵ) mass concentration 50 mg/L and adsorbent dose 1.00 g/L.
Keywords:sunflower seed shells  uranium  adsorption
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