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Addressing amorphization and transgranular fracture of B4C through Si doping and TiB2 microparticle reinforcing
Authors:Chawon Hwang  Jun Du  Qirong Yang  Azmi M Celik  Kent Christian  Qi An  Mark C Schaefer  Kelvin Y Xie  Jerry C LaSalvia  Kevin J Hemker  William A Goddard III  Richard A Haber
Affiliation:1. Department of Materials Science and Engineering, Rutgers, The State University of New Jersey, Piscataway, New Jersey, USA;2. Department of Materials Science and Engineering, Rutgers, The State University of New Jersey, Piscataway, New Jersey, USA

Present address: Materials Science Division, Lawrence Livermore National Laboratory, Livermore, CA 94550, USA.;3. Department of Chemical and Materials Engineering, University of Nevada, Reno, Reno, Nevada, USA;4. Department of Materials Science and Engineering, Rutgers, The State University of New Jersey, Piscataway, New Jersey, USA

Present address: Free Form Fibers, Saratoga Springs, NY 12866, USA.;5. Department of Materials Science and Engineering, Texas A&M University, College Station, Texas, USA;6. DEVCOM Army Research Laboratory, Aberdeen Proving Ground, Aberdeen, Maryland, USA;7. Department of Mechanical Engineering, Johns Hopkins University, Baltimore, Maryland, USA;8. Materials and Process Simulation Center, California Institute of Technology, Pasadena, California, USA

Abstract:Over the last two decades, many studies have contributed to improving our understanding of the brittle failure mechanisms of boron carbide and provided a road map for inhibiting the underlying mechanisms and improving the mechanical response of boron carbide. This paper provides a review of the design and processing approaches utilized to address the amorphization and transgranular fracture of boron carbide, which are mainly based on what we have found through 9 years of work in the field of boron carbides as armor ceramics.
Keywords:amorphization  boron carbide  doping  fracture behavior  reinforcement  titanium boride
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