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Addressing amorphization and transgranular fracture of B4C through Si doping and TiB2 microparticle reinforcing
Authors:Chawon Hwang  Jun Du  Qirong Yang  Azmi M. Celik  Kent Christian  Qi An  Mark C. Schaefer  Kelvin Y. Xie  Jerry C. LaSalvia  Kevin J. Hemker  William A. Goddard III  Richard A. Haber
Affiliation:1. Department of Materials Science and Engineering, Rutgers, The State University of New Jersey, Piscataway, New Jersey, USA;2. Department of Materials Science and Engineering, Rutgers, The State University of New Jersey, Piscataway, New Jersey, USA

Present address: Materials Science Division, Lawrence Livermore National Laboratory, Livermore, CA 94550, USA.;3. Department of Chemical and Materials Engineering, University of Nevada, Reno, Reno, Nevada, USA;4. Department of Materials Science and Engineering, Rutgers, The State University of New Jersey, Piscataway, New Jersey, USA

Present address: Free Form Fibers, Saratoga Springs, NY 12866, USA.;5. Department of Materials Science and Engineering, Texas A&M University, College Station, Texas, USA;6. DEVCOM Army Research Laboratory, Aberdeen Proving Ground, Aberdeen, Maryland, USA;7. Department of Mechanical Engineering, Johns Hopkins University, Baltimore, Maryland, USA;8. Materials and Process Simulation Center, California Institute of Technology, Pasadena, California, USA

Abstract:Over the last two decades, many studies have contributed to improving our understanding of the brittle failure mechanisms of boron carbide and provided a road map for inhibiting the underlying mechanisms and improving the mechanical response of boron carbide. This paper provides a review of the design and processing approaches utilized to address the amorphization and transgranular fracture of boron carbide, which are mainly based on what we have found through 9 years of work in the field of boron carbides as armor ceramics.
Keywords:amorphization  boron carbide  doping  fracture behavior  reinforcement  titanium boride
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