| Electrochemical corrosion behavior of carbon steel with bulk coating holidays |
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| 作者姓名： | Yiquan Song Cuiwei Du Xiaogang Li |
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| 作者单位： | [1]Material Science and Engineering School, University of Science and Technology Beijing, Beijing 100083, China [2]School of Material Science and Engineering, Inner Mongolia University of Science and Technology, Baotou 014010, China |
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| 摘 要： | With epoxy coal tar as the coating material, the electrochemical corrosion behavior of Q235 with different kinds of bulk coating holidays has been investigated with EIS （Electrochemical Impedance Spectroscopy） in a 3.5vo1% NaCI aqueous solution. The area ratio of bulk coating holiday to total coating area of steel is 4.91%. The experimental results showed that at free corrosion potential, the corrosion of carbon steel with disbonded coating holiday is heavier than that with broken holiday and disbonded ＆ broken holiday with time; Moreover, the effectiveness of Cathodic Protection （CP） of carbon steel with broken holiday is better than that with disbonded holiday and disbonded ＆ broken holiday on CP potential -850 mV （vs CSE）. Further analysis indicated that the two main reasons for corrosion are electrolyte solution slowly penetrating the coating, and crevice corrosion at steel/coating interface near holidays. The ratio of impedance amplitude （Z） of different frequency to minimum frequency is defined as K value. The change rate of K with frequency is related to the type of coating holiday.
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| 关 键 词： | 裂隙腐蚀 碳钢 电化学腐蚀 阴极保护 电化学阻抗光谱学 表面缺陷 |
| 收稿时间： | 2004-10-18 |
Electrochemical corrosion behavior of carbon steel with bulk coating holidays |
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| Yiquan Song Cuiwei Du Xiaogang Li.Electrochemical corrosion behavior of carbon steel with bulk coating holidays[J].Journal of University of Science and Technology Beijing,2006,13(1):37-43. |
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| Authors: | Yiquan Song Cuiwei Du Xiaogang Li |
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| Affiliation: | 1. Material Science and Engineering School, University of Science and Technology Beijing, Beijing 100083, China;School of Material Science and Engineering, Inner Mongolia University of Science and Technology, Baotou 014010, China
2. Material Science and Engineering School, University of Science and Technology Beijing, Beijing 100083, China |
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| Abstract: | With epoxy coal tar as the coating material, the electrochemical corrosion behavior of Q235 with different kinds of bulk coating holidays has been investigated with EIS (Electrochemical Impedance Spectroscopy) in a 3.5vol% NaCl aqueous solution.The area ratio of bulk coating holiday to total coating area of steel is 4.91%. The experimental results showed that at free corrosionpotential, the corrosion of carbon steel with disbonded coating holiday is heavier than that with broken holiday and disbonded & broken holiday with time; Moreover, the effectiveness of Cathodic Protection (CP) of carbon steel with broken holiday is better than that with disbonded holiday and disbonded & broken holiday on CP potential -850 mV (vs CSE). Further analysis indicated that the two main reasons for corrosion are electrolyte solution slowly penetrating the coating, and crevice corrosion at steel/coating interface near holidays. The ratio of impedance amplitude (Z) of different frequency to minimum frequency is defined as K value. The change rate of K with frequency is related to the type of coating holiday. |
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| Keywords: | bulk coating holidays EIS cathodic protection (CP) crevice corrosion |
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