| 自由基聚合宏观动力学的数学模型研究 |
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| 引用本文： | 喻发全,刘艳萍. 自由基聚合宏观动力学的数学模型研究[J]. 武汉化工学院学报, 1997, 0(4) |
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| 作者姓名： | 喻发全 刘艳萍 |
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| 摘 要： | 用数学模型方法研究了粘度对自由基聚合链增长速率、终止速率以及宏观动力学的影响规律，并得到相应的表达式；提出了凝胶化点和玻璃化点的处理方法，为探讨自由基聚合全过程规律提供了依据．
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| 关 键 词： | 自由基聚合；宏观动力学；凝胶效应；数学模型 |
Study on Macrokinetics and Gelation Effect of Radical Polymerization Based on a Mathematical Model |
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| Yu Faquan Liu Yanping. Study on Macrokinetics and Gelation Effect of Radical Polymerization Based on a Mathematical Model[J]. Journal of Wuhan Institute of Chemical Technology, 1997, 0(4) |
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| Authors: | Yu Faquan Liu Yanping |
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| Affiliation: | Yu Faquan Liu Yanping |
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| Abstract: | A brief formula for the relation between viscosity and propagation rate,termination rate and macrokinetics was obtained based on of a mathematical model.The relation between macrokinetics and microkinetics of radical polymerization was determined.A method of dealing with gelation and glass effect is also discussed. |
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| Keywords: | Radical polymerization Macrokinetics Gelation effect Mathematical model |
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