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SrAl2O4:Eu2+,Dy3+长余辉发光材料发光性能的研究
引用本文:耿秀娟,陈永杰,肖林久,邱关明. SrAl2O4:Eu2+,Dy3+长余辉发光材料发光性能的研究[J]. 沈阳化工学院学报, 2005, 19(3): 167-171
作者姓名:耿秀娟  陈永杰  肖林久  邱关明
作者单位:1. 沈阳化工学院应用化学系,辽宁,沈阳,110142
2. 沈阳化工学院应用化学系,辽宁,沈阳,110142;东北大学材料与冶金学院,辽宁,沈阳,110006
3. 长春理工大学材料与化工学院,吉林,长春,130022
基金项目:沈阳化工学院中青年科研启动基金(200413)
摘    要:采用微乳液法合成黄绿色SrAl2O4:Eu^2+,Dy^3+长余辉发光粉体,并且表征其晶体结构、激发光谱、发射光谱和余辉衰减特性.XRD分析表明:所合成的样品为SrAl2O4单斜晶系的晶体结构.激发波长的范围较宽,表明从紫外至可见光均可激发该发光材料.发射光谱主峰位于525 nm.样品在自然光照射后持续发出明亮的黄绿光.最后讨论微乳液体系中表面活性剂用量、激活剂和共激活剂浓度以及灼烧温度对产品发光性能的影响.

关 键 词:微乳液法 长余辉发光材料 激活剂
文章编号:1004-4639(2005)03-0167-05
收稿时间:2004-12-17
修稿时间:2004-12-17

Luminescence Properties of Long Afterglow Luminescent Materials SrAl2O4:Eu2+,Dy3+
GENG Xiu-juan,CHEN Yong-jie,XIAO Lin-jiu,QIU Guan-ming. Luminescence Properties of Long Afterglow Luminescent Materials SrAl2O4:Eu2+,Dy3+[J]. Journal of Shenyang Institute of Chemical Technolgy, 2005, 19(3): 167-171
Authors:GENG Xiu-juan  CHEN Yong-jie  XIAO Lin-jiu  QIU Guan-ming
Affiliation:1. Department of Applied Chemistry, Shenyang Institute of Chemical Technology, Shenyang 110142, China; 2. School of Material and Metallurgy, Northeastern University, Shenyang 110006, China; 3. School of Materials and Chemical Technology, Changchun University of Science and Technology, Changchun 130022, China
Abstract:long afterglow luminescent materials SrAl_2O_4:Eu~(2+),Dy~(3+) emitting yellow-green light was synthesized by microemulsion method.The phosphor quartz structure,the excitation spectrum,the emission spectrum and the long decay curve were measured and analyzed.XRD pattern indicates that the phosphor is with monoclinic SrAl_2O_4 crystal structure.The wide range of excitation wavelength indicates that the luminescent material could be excited by the light from ultraviolet ray to visible light.The main emission peak was at 520 nm.The sample excited by ultraviolet visible light can emit bright yellow-green light.The effect of the mass of surfactant,the concentration of radicalness and co-radicalness,sintering temperature on the luminescence properties of the samples were discussed.
Keywords:microemulsion   long afterglow luminescent materials   radicalness
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