| 含氟环氧丙烯酸酯树脂固化动力学研究 |
| |
| 引用本文： | 钱金明,史铁钧,盛敏刚.含氟环氧丙烯酸酯树脂固化动力学研究[J].上海涂料,2011,49(4):6-9. |
| |
| 作者姓名： | 钱金明 史铁钧 盛敏刚 |
| |
| 作者单位： | 1. 池州学院化学材料与工程实验中心,安徽池州,247000
2. 合肥工业大学化工学院,230009 |
| |
| 基金项目： | 安徽省高校省级自然科学重点项目，池州学院引进研究生科研启动项目 |
| |
| 摘 要： | 采用甲基丙烯酸甲酯(MMA)、甲基丙烯酸缩水甘油酯(GMA)、丙烯酸六氟丁酯(F6BA),通过溶液聚合法制备了含氟环氧丙烯酸酯树脂P(MMA/GMA/F6BA)。采用DSC研究了以己二酸为固化剂的固化反应,确定固化反应动力学方程和固化反应级数;采用FTIR跟踪固化反应过程,确定固化反应时间。
|
| 关 键 词： | 环氧丙烯酸酯 己二酸 固化反应 |
Study on Curing Kinetics of Epoxy Acrylate Resin Containing Fluorine |
| |
| QIAN Jin-ming,SHI Tie-jun,SHENG Min-gang.Study on Curing Kinetics of Epoxy Acrylate Resin Containing Fluorine[J].Shanghai Coatings,2011,49(4):6-9. |
| |
| Authors: | QIAN Jin-ming SHI Tie-jun SHENG Min-gang |
| |
| Affiliation: | QIAN Jin-ming1,SHI Tie-jun2,SHENG Min-gang1(1.Center of Chemical Engineering and Materials Science,Chizhou College,Anhui Chizhou,247000,China,2.School of Chemical Engineering,Hefei University of Technology,Anhui Hefei,230009,China) |
| |
| Abstract: | An epoxy acrylate resin containing fluorine was prepared by solution polymerization,with methyl methacrylate(MMA),glycidyl methacrylate(GMA)and hexafluorobutyl acrylate(F6BA)as monomers.The curing reaction of the resin/hexanedioic acid was studied by DSC,the equation and grade of curing kinetics was established.The process of the curing reaction was traced,and the time of the curing reaction was established by FTIR. |
| |
| Keywords: | epoxy acrylate resin hexanedioic acid curing reaction |
| 本文献已被 CNKI 维普 万方数据 等数据库收录！ |
|
