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白光LED用几种Eu^2+激活的红色荧光体的性能
引用本文:韩建伟,黄淋毅,王昌铃,石士考,刘行仁.白光LED用几种Eu^2+激活的红色荧光体的性能[J].照明工程学报,2009,20(3):18-23.
作者姓名:韩建伟  黄淋毅  王昌铃  石士考  刘行仁
作者单位:1. 深圳职业技术学院工业中心,深圳,518055
2. 福建省苍乐电子企业有限公司,福州,350007
3. 河北师范大学化学与材料科学学院,石家庄,050016
4. 中科院光机与物理研究所,长春,130021
摘    要:本文对固态照明白光LED用Eu^2+激活硫化钙、Eu^2+激活的氮化物和氮氧化物三种高效红色荧光体的物理化学和发光特性进行对比和分析。氮(氧)化物红色荧光体的性能稳定。四种材料适合用作InGaN蓝光LED光转换红色荧光体,和YAG:Ce黄粉组合,使制作的白光LED的显色指数Ra大大提高,有利实现LED普通照明。

关 键 词:氮化物荧光体  红色硫化物荧光体  白光LED  发光  显色指数

Characteristics of Red Eu2+-Activated-Phosphors for White Light-Emitting Diodes
Han Jianwei,Huang Linyi,Wang Changling,Shi Shikao,Liu Xingren.Characteristics of Red Eu2+-Activated-Phosphors for White Light-Emitting Diodes[J].China Illuminating Engineering Journal,2009,20(3):18-23.
Authors:Han Jianwei  Huang Linyi  Wang Changling  Shi Shikao  Liu Xingren
Affiliation:Han Jianwei, Huang Linyi, Wang Changling, Shi Shikao, Liu Xingren( 1. Shenzhen Polytechnic Industrial Centre, Shenzhen 518055 ; 2. Fujian Joinluck Electronic Enterprise Co. Ltd., Fuzhou 30007; 3. Colloge of Chemistry and Materials Science, Hebei Normal University, Shijiazhuang 050016 ; 4. Changchun Institute of Optics, Fine Mechanics and Physics, Chinese Academy of Science, Changchun
Abstract:In this paper, the luminescence characteristics of CaS:Eu, Sr2Si5N8:Eu system nitride and oxynitride red phosphors which are used in blue InGaN based white LED applications were investigated. CaS: Eu material is a effective phosphor and shows deep red light under the excitation of blue, green and yellow LED, but this alkali earth sulfide was easily damaged by moisture. Red Sr2 Si5 N8 : Eu nitride phosphor is effeciently excited by blue LED. This nitride has good luminescence properties, excellent thermal and chemical stability.
The good CIE chromaticity, the characteristics of excitation and emission spectra and re-absorption radiation transfer indicate that the CaS: Eu, Sr2Si5N8 : Eu and Sr2Si5OxN8-x: Eu system red phosphors can be used to generate red component in the phosphors-converted white LEDs having high color rendering inderx Ra: 90- 98.
Keywords:nitride phosphor  red sulfide phosphor  white LED  luminescence  color rendering index  
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