| 聚(N-苯基马来酰亚胺)-b-聚(4-乙烯基吡啶)-CdS纳米复合物的光学性质 |
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| 引用本文： | 董延茂,路建美,胡磊,纪顺俊.聚(N-苯基马来酰亚胺)-b-聚(4-乙烯基吡啶)-CdS纳米复合物的光学性质[J].功能材料与器件学报,2011,17(4):366-376. |
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| 作者姓名： | 董延茂 路建美 胡磊 纪顺俊 |
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| 作者单位： | 1. 江苏省有机化学重点实验室,苏州大学材化部,江苏苏州,215123;苏州科技学院化学与生物工程学院,江苏苏州,215009
2. 江苏省有机化学重点实验室,苏州大学材化部,江苏苏州,215123 |
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| 基金项目： | the Chinese Natural Science Foundation No.20876101 and No.21071105; major project of college and 30 universities JiangsuProvince(08KJA430004) |
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| 摘 要： | 用可逆加成锻炼链转移(RAFT)聚合方法合成了两亲性聚(N-苯基马来酰亚胺)-b-聚(4-乙烯基吡啶)-Cd2(PNPV-Cd2)高分子配合物.Cd2离子与4VP基团配位并与硫代乙酰胺分解产生的S2-离子原位生成CdS纳米粒子.聚(N-苯基马来酰亚胺)-b-聚(4-乙烯基吡啶)- CdS( PNPVCdS)中CdS的含...
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| 关 键 词： | RAFT N-苯基马来酰亚胺 纳米复合物 光致发光 非线性光学 |
Optical Properties of Poly(N-Phenylmaleimide)-b-Poly(4-Vinylpyridine)-CdS Nanocomposites |
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| Dong Yan-mao,Lu Jian-mei,Lei Hu,Ji Shun-jun.Optical Properties of Poly(N-Phenylmaleimide)-b-Poly(4-Vinylpyridine)-CdS Nanocomposites[J].Journal of Functional Materials and Devices,2011,17(4):366-376. |
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| Authors: | Dong Yan-mao Lu Jian-mei Lei Hu Ji Shun-jun |
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| Affiliation: | Dong Yan-mao1,2,Lu Jian-mei1,Lei Hu1,Ji Shun-jun1(1.Key Laboratory of Organic Chemistry of Jiangsu Province,College of chemistry,chemical engineering and materials science,Soochow University,Suzhou,215123,2.School of Chemistry and Bioengineering,Suzhou University of Science and Technology,215009) |
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| Abstract: | The amphipathic poly(N-phenylmaleimide)-b-poly(4-vinylpyridine)-Cd2+(PNPV-Cd2+) complex has been synthesized by reversible addition fragmentation chain transfer(RAFT) polymerization.The 4VP groups acted as the coordination sites for cadmium ion aggregations and nanosized CdS particles were successfully grown in situ at these sites with the release of S2-ions from thioacetamide.The CdS content and size in poly(N-phenylmaleimide)-b-poly(4-vinylpyridine)-CdS(PNPV-CdS) nanocomposites were controlled by the poly... |
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| Keywords: | RAFT N-phenylmaleimide nanocomposite photoluminescence nonlinear optical |
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