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方酶处理后絮凝法深度处理造纸废水
引用本文:马明玉,谢益民,洪卫.方酶处理后絮凝法深度处理造纸废水[J].中华纸业,2011,32(18):29-32.
作者姓名:马明玉  谢益民  洪卫
作者单位:1. 山东轻工业学院制浆造纸科学与技术教育部重点实验室,济南,250353
2. 山东轻工业学院制浆造纸科学与技术教育部重点实验室,济南250353;湖北工业大学制浆造纸工程研究所,武汉430068
3. 山东省环境保护科学研究设计院,济南,250014
基金项目:国家“十一五”水污染控制与治理重大专项资助项目(2008ZX07010-008-001)
摘    要:采用铁系仿酶Fe-多元羧酸复合物(简称Fe—cA)预处理二沉池出水,然后分别用聚合硫酸铁(PFS)、Al2(SO4)3、PAC三种絮凝剂进行絮凝处理。通过检测废水的COD、色度和TOC等指标,发现PFS的效果最佳。确定最优条件为:废水pH值6~7,PFS的投放量为200mg/L,PAM用量2mg/L,沉降时间3h。最终出水COD可降至80mg/L,色度为30倍,TOC降低至20mg/L。达到了饰4浆造纸工业水污染物排放标准》(GB3544-2008)的排放要求。铁系絮凝剂PFs用于造纸废水深度处理效率高、成本低、绿色环保,具有很好的应用前景。

关 键 词:中段废水  PFS  COD  TOC

A study on advanced treatment of paper mill effluent by different flocculants under the action of biomimetic
MAMing-yu,XIE Yi-min,HONG Wei.A study on advanced treatment of paper mill effluent by different flocculants under the action of biomimetic[J].China Pulp & Paper Industry,2011,32(18):29-32.
Authors:MAMing-yu  XIE Yi-min  HONG Wei
Affiliation:1.Key Laboratory of Paper Science and Technology of Ministry of Education, Shandong Institute of Light Industry, Jinan 250353, China; 2.Research Institute of Pulp and Paper Engineering, Hubei University of Technology, Wuhan 430068, China; 3.Shandong Academy of Environmental Science, Jinan 250014, China)
Abstract:In this study, Fe-polycarboxylic acid biomimetic complexes (Fe-CA) was used to pretreat the effluent water in secondary clarification pond, and then the water was flocculated by polymeric ferric sulfate (PFS), A12(SO4)3 and PAC respectively. By detecting the CODcr, colority and TOC, it was found that the PFS can reach the best effect, and the optimal condition of the wastewater treatment are as follows: pH at about 6-7, 200mg/L ofPFS, 2mg/L of PAM and sedimentation time 3h. At these conditions, the ultimate CODcr was 80rag/L, colority was 30times and TOC was 20 mg/L, which can meet the Discharge Standard of Water Pollutants for Pulp and Paper Industry (GB3544-2008). The PFS is of high efficiency, low cost, and friendly environmental, it will be widely used in advanced treatment of paper mill wastewater.
Keywords:washing & bleaching wastewater  PFS  COD  TOC  
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