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Effects of Mn-doping on TSDC and degradation of BaTiO3
Authors:Jaill Jeong  Young Ho Han
Affiliation:(1) Department of Materials Engineering, Sungkyunkwan University, 300 Chunchun-dong, Jangan-gu, Suwon, 440-746, Korea
Abstract:The effects of Mn-doping on TSDC (Thermally Stimulated Depolarization Current) and electrical degradation of BaTiO3 have been investigated. TSDCs of un-doped BaTiO3 and Ba(Ti1−x Mnx)O3−δ exhibited the three sharp TSDC peaks around phase transition temperatures. TSDC of Ba(Ti0.995Mg0.005)O2.995 increased gradually from 50C and this anomalous depolarization current kept going up well above the Curie temperature (∼130C). TSDCs of un-doped BaTiO3 and Ba(Ti0.995Mn0.005)O3−δ decreased in the temperature range above the Curie point, whereas a slight increase in TSDC was confirmed at the specimen of Ba(Ti0.99Mn0.01)O3−δ. TSDCs of Ba(Ti0.995−y Mg0.005Mny)O3−δ (y = 0.005, 0.01) were lower than that of Ba(Ti0.995Mg0.005)O2.995.
Keywords:Mn  BaTiO3            Mg  Electrical degradation  TSDC
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