Effect of dope extrusion rate on the formation and characterization of polyacrylonitrile nascent fibers during wet-spinning |
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Authors: | Gong-qiu Peng Yue-fang Wen Yong-gang Yang Lang Liu Wei Wang |
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Affiliation: | (1) Key Laboratory of Carbon Materials, Institute of Coal Chemistry, Chinese Academy of Sciences, 030001 Taiyuan, Shanxi, People’s Republic of China;(2) Graduate University of the Chinese Academy of Sciences, 100049 Beijing, People’s Republic of China |
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Abstract: | Polyacrylonitrile nascent fibers were prepared via the wet-spinning technique and a dimethyl sulphoxide/H2O coagulation bath system was adopted. The objective of this study was to investigate the influence of dope extrusion rates
on formation and characterization of nascent fibers. Nine different dope extrusion rates were adopted when other technique
parameters were kept steady. The surface morphology of nascent fibers was observed by field emission scanning electron microscopy.
The results showed that the dope extrusion rates played significant effects on the cross-section structure, surface morphology,
degree of crystallization, and sound velocity of the nascent fibers. With an increase of dope extrusion rate, the surface
roughness increased, and the sound velocity had a point of inflexion. Moreover, the degree of crystallization had a maximum
when the dope extrusion rate was 5.92 m/min. |
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Keywords: | Dope extrusion rate Polyacrylonitrile nascent fibers Shear rate Surface morphology Wet-spinning |
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