Temperature dependent electrical properties of 0.95[(K0.5Na0.5)(1-x)Ag x NbO3]-0.05LiSbO3 ceramics |
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Authors: | P. Palei P. Kumar S. Sonia |
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Affiliation: | 1. Department of Physics, National Institute of Technology, Rourkela, 769008, India 2. Department of Chemistry, National Institute of Technology, Rourkela, 769008, India
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Abstract: | Lead free 0.95[(K0.5Na0.5)1-x Ag x NbO3]-0.05LiSbO3 (KNAN-LS) ceramics with x?=?0.02, 0.04, 0.06 and 0.08 have been synthesized by conventional solid state reaction route (CSSR). XRD analysis confirmed the presence of a mixed structure for x?=?0.06. The orthorhombic?Ctetragonal polymorphic phase transition (PPT) temperature and the Curie temperature (Tc) decreased with the increase in Ag+ ion content in KNAN-LS ceramics. The relationship between the PPT of the ceramics and the temperature dependence of electrical properties of KNAN-LS ceramics were discussed in detail. The KNAN-LS ceramics with x?=?0.06 showed better piezoelectric and electromechanical properties (d33?=?227pC/N and kp?=?42.5?%). |
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