| 明胶反相乳化接枝改性胶粘剂的制备与性能研究 |
| |
| 引用本文： | 徐雷雷,邱建辉,陈国清,徐方圆.明胶反相乳化接枝改性胶粘剂的制备与性能研究[J].中国胶粘剂,2009,18(6). |
| |
| 作者姓名： | 徐雷雷 邱建辉 陈国清 徐方圆 |
| |
| 作者单位： | 1. 南京航空航天大学材料科学与技术学院,江苏,南京,210016
2. 上海博物馆,上海,200050 |
| |
| 基金项目： | 上海博物馆合作资助项目 |
| |
| 摘 要： | 在断裂或开裂古墨文物的修复中,必须使用与古墨本体相容性好、亲和力强的溶剂型胶粘剂。以古墨中的胶质材料明胶(GEL)为主,以丙烯酸丁酯(BA)、丙烯腈(AN)为辅,在两种非离子乳化剂复配的条件下,采用反相乳液接枝共聚法合成了一种专用于修复受损古墨的接枝改性明胶胶粘剂。采用红外光谱(FT-IR)技术对其结构进行了表征,试验探讨了各种因素对乳液稳定性、接枝率和接枝效率的影响。研究结果表明:当明胶的预处理时间为2h、搅拌速率为300r/min、反应温度为50℃、反应时间为2.5h和w(复合乳化剂)=10%(相对于油相而言)时,制取的接枝改性明胶胶粘剂能够满足古墨文物粘接修复的使用要求。
|
| 关 键 词： | 明胶 古墨 胶粘剂 反相乳液接枝共聚 丙烯酸丁酯 丙烯腈 |
Study on preparation and performance of graft modification adhesives of glutin by inverse emulsion polymerization |
| |
| XU Lei-lei,QIU Jian-hui,CHEN Guo-qing,XU Fang-yuan.Study on preparation and performance of graft modification adhesives of glutin by inverse emulsion polymerization[J].China Adhesives,2009,18(6). |
| |
| Authors: | XU Lei-lei QIU Jian-hui CHEN Guo-qing XU Fang-yuan |
| |
| Affiliation: | 1.Department of Material Science and Technology;Nanjing University of Aeronautics and Astronautics;Nanjing 210016;China;2. Shanghai Museum;Shanghai 200050;China |
| |
| Abstract: | In repair process of fractured or cracked ancient ink-sticks,the solvent type adhesives which had well compatibility and cohesiveness for ancient ink-stick noumenon must be used. With glutin(GEL) which was a gelatine material in ancient ink-sticks as main material,butyl acrylate(BA) and acrylonitrile(AN) as assistant material,a graft modification glutin adhesive for repairing damaged ancient ink-sticks was synthesized by inverse emulsion graft copolymerization under mix conditions of two types non-ionic emu... |
| |
| Keywords: | glutin ancient ink-stick adhesive inverse emulsion graft copolymerization butyl acrylate acry- lonitrile |
| 本文献已被 CNKI 万方数据 等数据库收录！ |
|
