| 耐热炸药5,5'-联四唑-1,1'-二氧钾盐的合成及热分解 |
| |
| 引用本文： | 王小军,张晓鹏,尚凤琴,鲁志艳,马骁,谭小艳,金韶华. 耐热炸药5,5'-联四唑-1,1'-二氧钾盐的合成及热分解[J]. 含能材料, 2016, 24(6): 528-531. DOI: 10.11943/j.issn.1006-9941.2016.06.002 |
| |
| 作者姓名： | 王小军 张晓鹏 尚凤琴 鲁志艳 马骁 谭小艳 金韶华 |
| |
| 作者单位： | 1. 甘肃银光化学工业集团有限公司,甘肃白银730900;北京理工大学材料科学与工程学院,北京100081;2. 甘肃银光化学工业集团有限公司,甘肃白银,730900;3. 北京理工大学材料科学与工程学院,北京,100081 |
| |
| 摘 要： | 以乙二肟为原料,用"一锅法"制备了5,5'-联四唑-1,1'-二羟基二水合物(BTO)的关键中间体二叠氮基乙二肟(DAG),以复分解反应合成了5,5'-联四唑-1,1'-二氧钾盐(PBTOX),采用元素分析、红外光谱对其结构进行了表征,用DTA-TG技术研究了PBTOX的热分解过程,用原子力显微技术(AFM)和洛伦兹接触共振(LCR)成像技术测试了PBTOX晶体的表面形貌和晶体力学性能,进行了感度测试。结果表明,PBTOX的晶体结构为层状结构,其5℃·min~(-1)升温速率下的分解峰顶温度为383℃。撞击感度爆炸百分数和摩擦感度爆炸百分数均为0%。
|
| 关 键 词： | 耐热炸药 5,5'-联四唑-1,1'-二氧钾盐(PBTOX) 合成 热分解 感度 |
| 收稿时间： | 2015-03-13 |
| 修稿时间： | 2015-06-17 |
Synthesis and Thermal Decomposition of a Heat-resistance Explosive Potassium Salts of 5,5'-Bistetrazole-1,1'-diolate |
| |
| WANG Xiao-jun,ZHANG Xiao-peng,SHANG Feng-qin,LU Zhi-yan,MA Xiao,TAN Xiao-yan and JIN Shao-hua. Synthesis and Thermal Decomposition of a Heat-resistance Explosive Potassium Salts of 5,5'-Bistetrazole-1,1'-diolate[J]. Chinese Journal of Energetic Materials, 2016, 24(6): 528-531. DOI: 10.11943/j.issn.1006-9941.2016.06.002 |
| |
| Authors: | WANG Xiao-jun ZHANG Xiao-peng SHANG Feng-qin LU Zhi-yan MA Xiao TAN Xiao-yan JIN Shao-hua |
| |
| Affiliation: | Research Institute of Gansu Yinguang Chemical Industry Group, Baiyin 730900, China ;College of Material Science and Engineering, Beijing Institute of Technology, Beijing, 100081, China,Research Institute of Gansu Yinguang Chemical Industry Group, Baiyin 730900, China,Research Institute of Gansu Yinguang Chemical Industry Group, Baiyin 730900, China,Research Institute of Gansu Yinguang Chemical Industry Group, Baiyin 730900, China,Research Institute of Gansu Yinguang Chemical Industry Group, Baiyin 730900, China,College of Material Science and Engineering, Beijing Institute of Technology, Beijing, 100081, China and College of Material Science and Engineering, Beijing Institute of Technology, Beijing, 100081, China |
| |
| Abstract: | |
| |
| Keywords: | heat-resistance explosive potassium 5,5'-bistetrazole-1,1'-diolate(PBTOX) synthesins thermal decomposition sensitivity |
| 本文献已被 CNKI 万方数据 等数据库收录！ |
| 点击此处可从《含能材料》浏览原始摘要信息 |
|
点击此处可从《含能材料》下载全文 |
|
