| N_2O_5/发烟硫酸体系一步法合成1-甲基-3,4,5-三硝基吡唑 |
| |
| 引用本文： | 吴霏,李永祥,郝彩丽,薛梅,王建龙,曹端林.N_2O_5/发烟硫酸体系一步法合成1-甲基-3,4,5-三硝基吡唑[J].含能材料,2016,24(6):618-620. |
| |
| 作者姓名： | 吴霏 李永祥 郝彩丽 薛梅 王建龙 曹端林 |
| |
| 作者单位： | 中北大学化工与环境学院,山西太原,030051 |
| |
| 摘 要： | 以1-甲基吡唑(1-MP)为原料,N_2O_5-发烟硫酸体系作为硝化剂,一步法硝化合成1-甲基-3,4,5-三硝基吡唑(MTNP),并采用红外光谱、核磁共振、元素分析和质谱表征了其结构。研究了N_2O_5质量分数、1-MP与N_2O_5摩尔比、反应温度和时间对MTNP产率的影响,并确定了最佳反应条件为:N_2O_5质量分数20%,n(1-MP)∶n(N_2O_5)=1∶5,温度为165℃,反应时间1.5 h,该条件下MTNP收率达60.32%。
|
| 关 键 词： | 1-甲基-3 4 5-三硝基吡唑(MTNP) N2O5 硝化 20％发烟硫酸 |
| 收稿时间： | 2015/11/10 0:00:00 |
| 修稿时间： | 2016/1/15 0:00:00 |
One Step Synthesis of MTNP with N2O5/Oleum System |
| |
| WU Fei,LI Yong-xiang,HAO Cai-li,XUE Mei,WANG Jian-long and CAO Duan-lin.One Step Synthesis of MTNP with N2O5/Oleum System[J].Chinese Journal of Energetic Materials,2016,24(6):618-620. |
| |
| Authors: | WU Fei LI Yong-xiang HAO Cai-li XUE Mei WANG Jian-long and CAO Duan-lin |
| |
| Affiliation: | Chemical and Enviroment Engineering, School of the North University of China, Taiyuan 030051, China,Chemical and Enviroment Engineering, School of the North University of China, Taiyuan 030051, China,Chemical and Enviroment Engineering, School of the North University of China, Taiyuan 030051, China,Chemical and Enviroment Engineering, School of the North University of China, Taiyuan 030051, China,Chemical and Enviroment Engineering, School of the North University of China, Taiyuan 030051, China and Chemical and Enviroment Engineering, School of the North University of China, Taiyuan 030051, China |
| |
| Abstract: | |
| |
| Keywords: | 1-methyl-3 4 5-trinitropyrazole(MTNP) N2O5 nitration 20% oleum |
| 本文献已被 CNKI 万方数据 等数据库收录！ |
| 点击此处可从《含能材料》浏览原始摘要信息 |
|
点击此处可从《含能材料》下载全文 |
|
