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Study on pitting process of 316L stainless steel by means of staircase potential electrochemical impedance spectroscopy
Authors:Zhi-jun Jia  Cui-wei Du  Cheng-tao Li  Zou Yi  Xiao-gang Li
Affiliation:School of Materials Science and Technology,University of science and Technology Beijing,Beijing 100083,China
Abstract:Pitting corrosion of 316L stainless steel in NaC1 solution was investigated by means of staircase potential electrochemical impedance spectroscopy (SPEIS).The investigation focused on the transition of stainless steel from the passive state to pitting corrosion.Based on the evolution of electrical parameters of the equivalent electrical circuit,it is suggested that the most probable mechanism of pit creation is the film breaking model.The result demonstrates that staircase potential electrochemical impedance spectroscopy is an effective method for the investigation of pitting corrosion.
Keywords:stainless steel  passivation  film  steel corrosion  pitting  electrochemical impedance spectroscopy
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